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基于构象和细胞形态变化的牦牛毛拉伸细化机理
引用本文:刘健,胡玉波,于伟东.基于构象和细胞形态变化的牦牛毛拉伸细化机理[J].毛纺科技,2009,37(10).
作者姓名:刘健  胡玉波  于伟东
作者单位:1. 东华大学纺织材料与技术实验室,上海,201620
2. 东华大学纺织材料与技术实验室,上海,201620;武汉科技学院,湖北,武汉,430074
摘    要:利用拉曼光谱技术对拉伸过程中牦牛毛纤维大分子构象的变化进行研究.结果表明,拉伸过程中牦牛毛纤维大分子始终发生a螺旋构象向口折叠构象的转变,同时在纤维大分子间还存在微结构滑移,且这一过程主要发生于拉伸过程的中后期.借助超声分离技术,对细化前后牦牛纤维皮质细胞形态的变化进行分析,发现纤维皮质细胞被拉长变细且不发生细胞间的滑移.基于研究结果确定,当拉伸倍数较大时,牦牛毛纤维的主拉伸机制为"部分大分子滑移"理论.

关 键 词:牦牛毛纤维  拉伸细化  微细结构  构象转变  细胞形态  超声分离  拉曼光谱

Mechanism research of yak hair stretching slenderization based on the changes of conformation and cell shape
LIU Jian,HU Yu-bo,YU Wei-dong.Mechanism research of yak hair stretching slenderization based on the changes of conformation and cell shape[J].Wool Textile Journal,2009,37(10).
Authors:LIU Jian  HU Yu-bo  YU Wei-dong
Affiliation:1;2;1.College of Textile;Donghua University;Shanghai 201620;China;2.Wuhan University of Science and Engineering;Wuhan 430074;China
Abstract:The macromolecular conformational changes of yak hair fiber have been investigated during stretching by Raman.The result showed that the transformation of macromolecular conformation was always taken place in yak hair fiber during stretching.Meanwhile,the slippage between macromolecule also exists in yak hair fibers,and which mainly take place in middle and later periods of slenderization.The shape changes of cortical cell of yak hair fiber have been analyzed before and after stretching slenderization by me...
Keywords:yak hair fiber  stretching slenderization  fine structure  conformational transformation  cell shape  ultrasonic separation  Raman spectroscopy  
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