Isotope geothermometry in the larderello geothermal field

The isotope geothermometers based on the ¹³C/¹²C fractionation between carbon dioxide and methane and on the ¹⁸O/¹⁶O fractionation between carbon dioxide and water vapour have been applied in Larderello geothermal field. The CO₂ - CH₄ thermometer gives temperatures which are 50–200°C higher than those measured at the well head. The distribution of the isotopic temperatures within the field follows more or less similar patterns to those given by the well-head temperatures. They are believed to reflect the temperatures of formation of CO₂ and CH₄.The CO₂ - H₂O thermometer gives the temperature of the geothermal reservoirs tapped, and the difference between the isotopic temperature and the temperature measured at the well head is a measure of the cooling undergone by geothermal fluid on its way up to the surface.