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UV/Fenton法对诺氟沙星的降解与矿化
引用本文:吴健,熊振湖.UV/Fenton法对诺氟沙星的降解与矿化[J].天津城市建设学院学报,2008,14(4):259-262.
作者姓名:吴健  熊振湖
作者单位:天津城市建设学院,环境与市政工程系,天津,300384
基金项目:天津市自然科学基金重点资助项目  
摘    要:研究了UV/Fenton反应对氟喹诺酮类抗生素诺氟沙星的降解与矿化过程。内容包括:H2O2,Fe^2+的初始浓度、pH值等因素对UV/Fenton反应的影响。结果表明,对于UV/H2O2/Fe^2+反应系统的诺氟沙星的降解,其降解速率受反应条件的强烈影响。诺氟沙星初始浓度为25mg/L时,适宜的操作条件是:初始pH值为4,FeSO4浓度为0.72mmol/L,H2O2浓度为23.50mmol/L。对要求总有机碳(TOC)去除率高的氟喹诺酮类抗生素的处理,UV/Fenton类型反应在技术上是可行的。

关 键 词:高级氧化反应  UV/Fenton  抗生素  诺氟沙星  光氧化  矿化

Study on Degradation and Mineralization of Norfloxacin by UV/Fenton Processes
WU Jian,XIONG Zhen-hu.Study on Degradation and Mineralization of Norfloxacin by UV/Fenton Processes[J].Journal of Tianjin Institute of Urban Construction,2008,14(4):259-262.
Authors:WU Jian  XIONG Zhen-hu
Affiliation:(Department of Environmental and Municipal Engineering, TIUC, Tianjin 300384, China)
Abstract:The degradation and mineralization of fluoroquinolone antibiotics norfloxacin by UV/Fenton processes is inves-tigated. The degradation rate is strongly dependent on the pH,initial concentrations of Fe2 and H2O2. Result shows that with initial concentration of 25,mg/L, the optimum conditions are obtained at pH 4 for the UV/H2O2/Fe2 systems. The optimum concentration of FeSO4 is 0.72,mmol/L and H2O2 is 23.50 mmol/L. It is suggested that reactions of UV/Fenton type are available techniques for the treatment of such types of fluoroquinolone antibiotics which requires high levels of TOC re- moval.
Keywords:UV/Fenton
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