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醋酸/水萃取精馏的模拟
引用本文:胡兴兰,苗文俊,周荣琪.醋酸/水萃取精馏的模拟[J].计算机与应用化学,2004,21(6):828-830.
作者姓名:胡兴兰  苗文俊  周荣琪
作者单位:1. 承德石油高等专科学校化工系,河北,承德,067000
2. 清华大学化工系,北京,100084
摘    要:利用PRO/Ⅱ软件对醋酸/水的萃取精馏进行了模拟。采用Hayden-O’Connell方程计算逸度系数,NRTL方程计算活度系数。模拟结果显示,与普通精馏相比,萃取精馏工艺的再沸器热负荷降低了51.8%,生产每吨醋酸耗费蒸汽量由8.9t降至4.6t,说明在同样的分离指标下,萃取精馏法分离醋酸/水要优于普通精馏法。

关 键 词:模拟  萃取精馏  醋酸/水  PRO/Ⅱ

Simulation of extractive distillation of acetic acid-water
HU XingLan,MIAO WenJun,Zhou Rongqi.Simulation of extractive distillation of acetic acid-water[J].Computers and Applied Chemistry,2004,21(6):828-830.
Authors:HU XingLan  MIAO WenJun  Zhou Rongqi
Affiliation:HU XingLan~1 MIAO WenJun~1 and ZHOU RongQi~2
Abstract:Extractive distillation of acetic acid and water was simulated with the software PRO/II. To provide data for the simulation, the fugacity coefficients were calculated by Hayden-O'Connell equation, and the activity coefficients by NRTL equation. Simulation results showed that extractive distillation was superior to conventional distillation in separation of acetic acid and water, which heat duties of the reboilers was reduced by 51.8% , and the corresponding heating steam was reduced from 8.9 tons to 4.6 tons per ton acetic acid produced.
Keywords:simulation  extractive distillation  acetic acid-water  PRO/II  
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