| 甲醇水蒸气重整制氢的铜基催化剂研究 |
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| 引用本文： | 石国军,崔群,王小尚,姚虎卿.甲醇水蒸气重整制氢的铜基催化剂研究[J].天然气化工,2005,30(5):5-9. |
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| 作者姓名： | 石国军 崔群 王小尚 姚虎卿 |
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| 作者单位： | 1. 南京工业大学化学化工学院,南京,210009
2. 中国石油化工股份有限公司天然气分公司,北京,100029 |
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| 摘 要： | 制备了用于甲醇水蒸气重整制氢的Cu/Zn/Al和Cu/Zn/Al/Ce系列催化剂,考察了不同组成、不同的催化剂制备方法、反应温度等因素对催化剂性能的影响,对催化剂前体进行了热分析,对部分焙烧后催化剂进行了X射线衍射分析。结果表明:铜基催化剂对甲醇水蒸气重整制氢反应有较好的活性和选择性,合适的组成是Cu∶Zn∶Al的原子质量百分比为47.5∶47.5∶5,在210℃的转化率达到100%;铈的添加对Cu/Zn/Al催化剂的低温活性有较大的提高,1%的铈使Cu60Zn30Al10在210℃的转化率从85.9%提高到97.6%;并流共沉淀法和热分解法制备的催化剂都具有较好的催化性能。
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| 关 键 词： | 甲醇 氢气 水蒸气重整 催化剂 Cu/Zn/Al/Ce |
| 文章编号： | 1001-92119（2005）05-05-05 |
| 收稿时间： | 2005-03-10 |
| 修稿时间： | 2005年3月10日 |
Investigation on the Cu-based Catalysts for Steam Reforming of Methanol |
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| SHI Guo-jun,CUI Qun,Wang Xiao-shang,YAO Hu-qing.Investigation on the Cu-based Catalysts for Steam Reforming of Methanol[J].Natural Gas Chemical Industry,2005,30(5):5-9. |
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| Authors: | SHI Guo-jun CUI Qun Wang Xiao-shang YAO Hu-qing |
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| Abstract: | A series of Cu/Zn/Al and Cu/Zn/Al/Ce catalysts were tested to prepare hydrogen by steam reforming of methanol(MSR).Catalyst compositions and preparation methods as well as reaction temperatures were investigated.The results show that the Cu-based catalysts has rather high activity and selectivity.The addition of cerium has a good promotion to the activity of Cu/Zn/Al catalysts.The catalysts that are prepared by coprecipitation and thermal decomposition have good catalytic performances and are suitable for MSR. |
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| Keywords: | methanol hydrogen steam reforming catalyst Cu/Zn/Al/Ce |
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