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铝镇静钢氮含量控制分析
引用本文:贾毅,刘春阳,韩少伟,王彦锋,李春奇,万力凝.铝镇静钢氮含量控制分析[J].中国冶金,2021,31(3):116-121.
作者姓名:贾毅  刘春阳  韩少伟  王彦锋  李春奇  万力凝
作者单位:北京首钢股份有限公司炼钢作业部, 河北 唐山 064400
摘    要:在炼钢过程中,将成品氮质量分数稳定控制在0.003%以下存在一定难度。对铝镇静钢而言,常规生产流程为BOF-RH-CC,增氮和脱氮在每个工艺环节都可能会发生。本研究进行了9炉工业试验以研究冶炼全过程中氮含量的变化。结果表明,转炉冶炼终点钢中氮含量随碳氧积的增加而增加,而碳氧积反映了转炉底吹搅拌效果。出钢过程发生了增氮现象,合金化时间越长,转炉终点碳含量越低,出钢口的使用炉数越多,增氮量越大。对于RH过程中脱氮行为,RH浸渍管越新,脱氮越多。根据所得结论,提出了控制钢中氮含量的可行措施。

关 键 词:铝镇静钢  全流程  增氮  脱氮  热力学  动力学  

Analysis of nitrogen content control in Al-killed steel
JIA Yi,LIU Chun-yang,HAN Shao-wei,WANG Yan-feng,LI Chun-qi,WAN Li-ning.Analysis of nitrogen content control in Al-killed steel[J].China Metallurgy,2021,31(3):116-121.
Authors:JIA Yi  LIU Chun-yang  HAN Shao-wei  WANG Yan-feng  LI Chun-qi  WAN Li-ning
Affiliation:Steelmaking Department, Beijing Shougang Co., Ltd., Tangshan 064404, Hebei, China
Abstract:In the process of steelmaking, it is difficult to control the nitrogen mass fraction of finished product below 0.003%. For the production of Al-killed steel, the general manufacture routine is BOF-RH-CC, and nitrogen absorption and desorption could happen in every process. In order to study the change of nitrogen content in the whole smelting process, nine industrial tests were carried out. The results show that the nitrogen content in steel at the steelmaking end-point increases with the increase of carbon and oxygen accumulation, which reflects the stirring effect of bottom blowing. During tapping, nitrogen absorption occurred, and the longer the alloying time is, the lower the carbon content at the steelmaking end-point is. The more the number of taps used, the greater the amount of nitrogen absorption increased. For the nitrogen desorption behavior during RH process, the newer the RH immersed nozzle is, the more nitrogen desorption occurs. According to the conclusion, the feasible measures to control the nitrogen content in steel are proposed.
Keywords:Al-killed steel                                                      whole process                                                      nitrogen absorption                                                      nitrogen desorption                                                      thermodynamics                                                      kinetics                                      
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