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Catalysts for selective hydrogenation of soybean oil.1 II. Commercial catalysts
Authors:C. H. Riesz  H. S. Weber
Affiliation:(1) Illinois Institute of Technology Research Institute, Chicago, Illinois
Abstract:
A survey of commercial hydrogenation catalysts demonstrated the higher selectivity (SL= 2.4s-2.7) of certain platinum, palladium and rhodium catalysts for hydrogenating linolenic components in soybean oil. Nickel catalysts generally showed selectivities below SL=2.0 although skeletal nickel achieved higher values.Trans-isomers were in the range 7.8s-15.4% for the above noble metal catalysts. Nickel catalysts provide a lesser degree of isomerization, 5.2s-7.4% oftrans-isomers for the most selective catalysts. Presented at the AOCS Meeting at Toronto, 1962.
Keywords:
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