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Optical and mechanical properties of transparent acrylic based polyurethane nano Silica composite coatings
Authors:Reza Eslami  Rouhollah Bagheri  Yasser Hashemzadeh  Mehdi Salehi
Affiliation:1. Department of Chemical Engineering, Polymer Group, Isfahan University of Technology, 84146 Isfahan, Iran;2. Department of Materials Engineering, Isfahan University of Technology, 84146 Isfahan, Iran
Abstract:The aim of this work is to investigate the effect of two types of nano Silica (precipitated and fumed) with various concentrations on the optical and mechanical properties of transparent polyurethane acrylic based nano composite coatings. Transparency, gloss, UV absorption, adhesion strength and impact resistance of the samples have been measured. The gloss of the film samples remains unchanged compared to the reference film sample up to 2 wt.% (weight percent) for both types of nanoparticles. The samples containing 4 and 6 wt.% nano Silica show reduction in the gloss property by 4.3% and 5.3%, respectively, for fumed samples and 1.8% and 23% for precipitated samples. The film samples show increase in light absorption in the wavelength region of 250–2000 nm by increasing the content of nano Silica. Also cross cut and pull-off test results show that a good adhesion to steel can be obtained (5B for cross-cut, 7 MPa for pull-off) and no changes in impact strength of the samples with respect to the reference have been observed.
Keywords:Nano composite   Acrylic based polyurethane   Nano Silica   Silica nanoparticles   Fumed nano Silica   Precipitated nano Silica
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