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石墨烯-多壁碳纳米管协同增强环氧树脂复合材料的低温力学性能
引用本文:沈小军,孟令轩,付绍云.石墨烯-多壁碳纳米管协同增强环氧树脂复合材料的低温力学性能[J].复合材料学报,2015,32(1):21-26.
作者姓名:沈小军  孟令轩  付绍云
作者单位:1. 嘉兴学院 材料与纺织工程学院, 嘉兴 314000; 2. 中国科学院理化技术研究所, 北京 100190
摘    要:为了提高环氧树脂的低温力学性能,采用石墨烯与多壁碳纳米管(MWCNTs)协同改性环氧树脂,系统研究了石墨烯-MWCNTs/环氧树脂复合材料的室温(RT)和低温(77K)力学性能。结果表明:当石墨烯的质量分数为0.1wt%,MWCNTs的质量分数为0.5wt%时,纳米填料的加入可同时改善环氧树脂的低温拉伸强度、弹性模量和冲击强度;在此最佳含量下,石墨烯-MWCNTs/环氧树脂复合材料在RT和77K时的拉伸强度皆达到最大值,比纯环氧树脂的拉伸强度分别提高了11.04%和43.78%。石墨烯和MWCNTs能协同提高环氧树脂的低温力学性能。

关 键 词:多壁碳纳米管  石墨烯  环氧树脂  复合材料  低温力学性能  
收稿时间:2013-12-25

Cryogenic mechanical properties of epoxy composites synergistically reinforced by graphene-multi-walled carbon nanotubes
SHEN Xiaojun,MENG Lingxuan,FU Shaoyun.Cryogenic mechanical properties of epoxy composites synergistically reinforced by graphene-multi-walled carbon nanotubes[J].Acta Materiae Compositae Sinica,2015,32(1):21-26.
Authors:SHEN Xiaojun  MENG Lingxuan  FU Shaoyun
Affiliation:1. College of Materials and Textile Engineering, Jiaxing University, Jiaxing 314000, China; 2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Abstract:In order to enhance the cryogenic mechanical properties of epoxy, graphene and multi-walled carbon nanotubes (MWCNTs) were used to modify epoxy synergistically. Room temperature (RT) and cryogenic (77 K) mechanical properties of graphene-MWCNTs/epoxy composites were systematically studied. The results show that simultaneous enhancements in cryogenic tensile strength, elastic modulus and impact strength can be achieved with 0.1wt% graphene and 0.5wt% MWCNTs. At this optimal formulation, the tensile strength of graphene-MWCNTs/epoxy composites reaches the highest value at both RT and 77 K, and is increased by 11.04% and 43.78% respectively, compared to pure epoxy. The cryogenic mechanical properties of epoxy can be synergistically enhanced by graphene and MWCNTs.
Keywords:multi-walled carbon nanotubes  graphene  epoxy  composites  cryogenic mechanical properties
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