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Review MXenes as a new type of nanomaterial for environmental applications in the photocatalytic degradation of water pollutants
Authors:Xiaofang Feng  Zongxue Yu  Yuxi Sun  Runxuan Long  Mengyuan Shan  Xiuhui Li  Yuchuan Liu  Jianghai Liu
Abstract:Two-dimensional titanium carbide (MXene) with an adjustable bandgap (0.92–1.75eV), excellent structural stability, high conductivity and hydrophilicity has always been a hotspot in the field of environmental photocatalysis. However, the rapid recombination of light-excited carriers of a single photocatalytic material decreases quantum efficiency and photocatalytic performance. The modification of MXene could overcome these problems to improve photocatalytic properties. Among various improvement strategies, the composition of MXene heterostructure and Schottky junction is an effective and straightforward strategy for adjusting electronic structure and accelerating photocatalytic performance. This review aims to design typical, cost-effective heterojunctions and Schottky junctions and their progress, mechanisms, and trends in environmental organic pollutants' degradation. This review detailed the heterogeneous catalytic mechanism of MXene-based photocatalysts for the degradation of organic pollutants. It is discussed the way to improve the photocatalytic performance of MXene by constructing heterojunction and Schottky junction. The surface properties, catalyst performance and pollution management of various MXene-based catalysts were compared, and then some dilemmas and application strategies of MXene development were analyzed in depth. This review can open up ideas for new approaches and provide valuable clues for designing MXene as a cocatalyst to develop more effective photocatalysts for practical application in environmental pollution management.
Keywords:Heterojunction  Photocatalytic degradation  MXene  Charge transfer
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