Relativistic multireference Møller-Plesset perturbation theory calculations of the energy levels and transition probabilities in Ne-like xenon, tungsten, and uranium ions |
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Authors: | Marius J. Vilkas |
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Affiliation: | Department of Chemistry, University of Puerto Rico, P.O. Box 23346, San Juan, PR 00931-3346, USA |
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Abstract: | Relativistic multireference many-body Møller-Plesset perturbation theory (MR-MP) calculations have been performed on neonlike xenon, tungsten, and uranium ions. The 2s−1n? and 2p−1n? (n ? 5, ? ? 4) energy levels, lifetimes and transition probabilities are reported. The second-order MR-MP calculation of energy levels included mass shifts, frequency-dependent first-order Breit correction and Lamb shifts. The calculated transition energies are compared with other theoretical and experimental data. The synthetic radiative spectra is presented for different wavelength regions. |
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