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热分解动力学在含能材料中的应用
引用本文:张涛,陈明华,贾昊楠,贾晓彪,常文平,陈永康.热分解动力学在含能材料中的应用[J].爆破器材,2013(6):52-56.
作者姓名:张涛  陈明华  贾昊楠  贾晓彪  常文平  陈永康
作者单位:军械工程学院军械技术研究所河北石家庄,050000
摘    要:文章主要介绍了热分解动力学在含能材料中的重要性,列举了热分解动力学的主要分析方法及几种常用的反应机理,并对其进行简要分析。热分析技术具有快捷简便、准确度高以及适用范围广的特点,在含能材料的热分解动力学中发挥重要作用。热分解动力学广泛应用于含能材料的动力学参数的求解、反应机理的推断以及动力学补偿效应的确定,为其有效使用寿命的预测以及安全性能的评定等提供科学依据。同时,热分析技术的自身完善以及与其他技术的联机使用将促进热分解动力学的不断发展。

关 键 词:含能材料  热分解动力学  反应机理  动力学补偿效应  寿命预测

Application of Thermal Decomposition Kinetics in Energetic Materials
ZHANG Tao,CHEN Minghua,JIA Haonan,JIA Xiaobiao,CHANG Wenping,CHEN Yongkang.Application of Thermal Decomposition Kinetics in Energetic Materials[J].Explosive Materials,2013(6):52-56.
Authors:ZHANG Tao  CHEN Minghua  JIA Haonan  JIA Xiaobiao  CHANG Wenping  CHEN Yongkang
Affiliation:Ordnance Institute of Technology, Ordnance Engineering College (Hebei Shijiazhuang, 050000)
Abstract:The importance of thermal decomposition kinetics in energetic materials was introduced. The main analysis methods of thermal decomposition kinetics and several kinds of reaction mechanism were enumerated and analyzed. Because thermal analysis technology has many advantages including simple and quick operation, high accuracy and extensive appli- cation, it plays an important role in the thermal decomposition kinetics of energetic materials. Therulal decomposition kinetic is widely applied in the obtaining of kinetic parameters, the inference of reaction mechanism and kinetic compensation effect for energetic materials. It provides scientific basis for the prediction of service life and evaluation of safety performance of energetic material. Meanwhile, self-improvement of thermal analysis techniques and combination with other laboratory instruments will promote the development of thermal analysis kinetics.
Keywords:energetic materials  thermal decomposition kinetics  reaction mechanism  kinetic compensation effect  prediction of service life
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