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纳米重晶石/环氧复合钢板涂层材料机械及耐腐蚀性能的研究
引用本文:杭建忠,施利毅,娄燕燕,钟庆东,张剑平.纳米重晶石/环氧复合钢板涂层材料机械及耐腐蚀性能的研究[J].功能材料,2006,37(12):2003-2006.
作者姓名:杭建忠  施利毅  娄燕燕  钟庆东  张剑平
作者单位:1. 上海大学,环境与化学工程学院,上海,201800
2. 上海大学,纳米科学与技术研究中心,上海,200444;上海大学,理学院,上海,200444
3. 上海大学,分析测试中心,上海,200444
4. 上海电力学院,环境工程系,上海,200090
5. 上海大学,理学院,上海,200444
基金项目:国家科技攻关世博科技专项资助项目 , 上海市纳米科技专项基金
摘    要:研究了纳米重晶石改性方法,以及纳米重晶石添加量对钢板涂层硬度、T弯、应变和耐盐雾等性能的影响,并通过扫描电镜观察了纳米重晶石/环氧复合涂层断面以及粒子在基体中的分散状况.研究表明,使用5%硬脂酸钠改性后的纳米重晶石活化指数最大,且具有良好的分散性;纳米重晶石添加量为1.0%时,涂层性能有较大的提高,T弯从4T改善到2T;耐盐雾时间也由720h增加到1096h,提高了20%以上.另外,从涂层断面观察发现,纳米重晶石添加量为1.0%时,颗粒较均匀地分散,粘接紧密,形成较为致密的复合涂层.

关 键 词:纳米重晶石  涂层  硬度  T弯  盐雾
文章编号:1001-9731(2006)12-2003-04
收稿时间:2006-04-18
修稿时间:2006-09-18

Study on the mechanical properties and corrosion resistance properties of nanometer barite /epoxy composite paint film material
HANG Jian-zhong,SHI Li-yi,LOU Yan-yan,ZHONG Qing-dong,ZHANG Jian-ping.Study on the mechanical properties and corrosion resistance properties of nanometer barite /epoxy composite paint film material[J].Journal of Functional Materials,2006,37(12):2003-2006.
Authors:HANG Jian-zhong  SHI Li-yi  LOU Yan-yan  ZHONG Qing-dong  ZHANG Jian-ping
Affiliation:1. School of Environmental and Chemical Engineering, Shanghai University, Shanghai 201800, China; 2. Research Center of Nanoscience and Nanotechnology of Shanghai University,Shanghai 200444,China; 3. Instrumental Analysis and Research Center of Shanghai University, Shanghai 200444, China; 4. Department of Environmental Engineering, Shanghai University of Electric Power,Shanghai 200090,China; 5. School of Science, Shanghai University, Shanghai 200444, China
Abstract:The modification of nanometer barite and effect of dosage of nanometer barite on the hardness,T-bending performance,the strain,and salt spray test of the paint films have been investigated in detail. The fractured surface of nanometer barite/epoxy composite paint films and the disperse characters of stuffing were observed by SEM images. The results indicated that nanometer barite modified with 5% sodium stearate possessed the biggest activation indices,and better dispersibility. The performances of composite paint film adding 1.0 % modified nanometer barite were improved largely, the T-bending was improved from 4T to 2T,and the corrosion resistance increased 20% with its retardation time from 720- 1096h before showing blisters. Moreover, nanometer particles dispersed uniformly in the paint film was characterized by SEM images.
Keywords:nanometer barite  paint film  hardness  T bending  salt spray
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