| 微波催化合成四苯基卟啉 |
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| 引用本文： | 王征远,江桂英.微波催化合成四苯基卟啉[J].精细化工中间体,2004,34(1):38-39. |
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| 作者姓名： | 王征远 江桂英 |
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| 作者单位： | 扬州职业大学,轻纺工程系,江苏,扬州,225002 |
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| 摘 要： | 在有机溶剂体系中,利用微波催化苯甲醛、吡咯合成四苯基卟啉。最佳反应条件为:二甲苯溶剂100ml,对硝基苯甲酸催化剂1.8g,苯甲醛0.02mol、吡咯0.02mol,微波功率210W,辐射时间15min,产率达到52 9%,经重结晶,双组分紫外光谱法测定四苯基卟啉纯度达96%。
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| 关 键 词： | 四苯基卟啉 微波催化 合成 |
| 文章编号： | 1009-9212(2004)01-0038-02 |
| 修稿时间： | 2003年6月30日 |
The Synthesis of Tetraphenyl-Porphyrin(TPP) Under Microwave Irradiation |
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| WANG Zheng-yuan,JIANG Gui-ying.The Synthesis of Tetraphenyl-Porphyrin(TPP) Under Microwave Irradiation[J].Fine Chemical Intermediates,2004,34(1):38-39. |
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| Authors: | WANG Zheng-yuan JIANG Gui-ying |
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| Abstract: | The synthetic methods of meso-teraphenylporphyrin(TPP) under microwave irradiation in organic solvent were researched. The optimum reaction conditions are as follows: 1.8g p-nitrobentoic acid as the catalyst in 100?ml xylene, 0.02mol phenylformaldehyde, 0.02?mol pyrrole, 210W microwave power and 15?min microwave irradiation. The yield reachs 52.9%. The purity of the product for TPP was 96% for recrystallization by double Wave-UV valuing. |
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| Keywords: | teraphenylporphyrin microwave catalytic synthesize |
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