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CH3I在532nm及455.5nm激光作用下多光子电离研究
引用本文:章莲蒂,魏杰.CH3I在532nm及455.5nm激光作用下多光子电离研究[J].量子电子学报,1998,15(3):293-296.
作者姓名:章莲蒂  魏杰
摘    要:本文利用飞行时间质谱仪研究了532nm和455.5nm激光作用下CH3I分子的多光子电离解离(MPID)。在532nm激光作用下,CH3I分子由双光子激发到A带的A2态,它的MPID属母体离子阶梯模式;在455.5nm激光作用下,CH3I分子由双光子激发到A带的3E态,它的MPID属中性碎片光电离模式。

关 键 词:多光子电离  碘甲烷  飞行时间质谱

The Study of Multiphoton Ionization Dissociation of CH_3I with 532 nm and 455.5 nm
Zhang Liandi,Wei Jie,Fang Li,Jiang Yunyun,Zhang Shudong,Guo Wenyue,Zhang Bin,Cai Jiye.The Study of Multiphoton Ionization Dissociation of CH_3I with 532 nm and 455.5 nm[J].Chinese Journal of Quantum Electronics,1998,15(3):293-296.
Authors:Zhang Liandi  Wei Jie  Fang Li  Jiang Yunyun  Zhang Shudong  Guo Wenyue  Zhang Bin  Cai Jiye
Abstract:The multiphoton ionization-dissociation spectra of methyl iodide are given by 532 nm or 455.5 nm laser excitation in this paper. CH3I molecule is two-photon resonantly exited to 1AZ state of A-band by 532 nm laser excitation, and its MPID belongs to parent-ion ladder mechanism; CH3I molecule is two-photon resonantly exited to 3E state of A-band by 455.5 nm laser excitation, and its MPID belongs to neutral-fragment photoionization mechanism.
Keywords:multiphoton ionization  methyl iodide  time-of-flight mass spectrum
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