| Ca3(PO4)2:RE3+ (RE=Eu,Dy,Ce,Tb) 荧光粉的制备及其发光特性 |
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| 引用本文： | 孟涛,胡正发,张伟,王雄庭,叶定华,王银海,罗莉,王伟,杜姬芳.Ca3(PO4)2:RE3+ (RE=Eu,Dy,Ce,Tb) 荧光粉的制备及其发光特性[J].量子电子学报,2013,30(3):303-309. |
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| 作者姓名： | 孟涛 胡正发 张伟 王雄庭 叶定华 王银海 罗莉 王伟 杜姬芳 |
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| 作者单位： | 1 广东工业大学物理与光电工程学院，广东 广州 510006；
2 中山市鸿宝电业有限公司，广东 中山 518476 |
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| 基金项目： | 广东省重大科技专项，佛山市南海区绿色照明产业发展(技术创新)专项 |
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| 摘 要： | 采用高温固相法合成了Ca3(PO4)2:RE3+(RE = Eu, Dy, Ce, Tb)系列发光材料，研究了其发光性质。研究表明Ca3(PO4)2: RE3+ 在紫外区域均能有效被激发，有很强的荧光发射，且发光范围覆盖蓝到红光波段，是一类可以紫外激发实现白光LED用的潜在荧光粉。在0.005到0.03 mol 浓度范围内，Eu，Dy和Ce掺杂的荧光粉的发光都发生了浓度淬灭，分别对应于0.025，0.025和0.02 mol，而Tb3+掺杂的样品的表现出高的发光淬灭浓度。
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| 关 键 词： | 材料 荧光粉 高温固相法 磷酸盐基质 白光LED |
| 收稿时间： | 2012-05-07 |
| 修稿时间： | 2012-11-27 |
Preparation and luminescence properties of Ca3(PO4)2∶RE3+(RE=Eu,Dy, Ce,Tb) phosphors |
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| MENG Tao,HU Zheng-fa,ZHANG Wei,WANG Xiong-ting,YE Ding-hua,WANG Yin-hai,LUO Li,WANG Wei,DU Ji-Fang.Preparation and luminescence properties of Ca3(PO4)2∶RE3+(RE=Eu,Dy, Ce,Tb) phosphors[J].Chinese Journal of Quantum Electronics,2013,30(3):303-309. |
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| Authors: | MENG Tao HU Zheng-fa ZHANG Wei WANG Xiong-ting YE Ding-hua WANG Yin-hai LUO Li WANG Wei DU Ji-Fang |
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| Affiliation: | 1 College of Physics & Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, China;
2 Zhongshan Hongbao Electrical Co. Ltd., Zhongshan 518476 , China |
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| Abstract: | A series of phosphors Ca3(1-x)(PO4)2: xRE3+(RE = Eu, Dy, Ce, Tb) have been prepared by a high temperature solid-state reaction method. Their luminescence properties were investigated. The results indicated that all samples could be effectively excited by ultraviolet light with the range from blue to red light, and they are the potential phosphors to obtain white LED excited by ultraviolet light.In the range of 0.005 to 0.03 mol, photoluminescence quenching concentration of Eu3+, Dy3+, and Ce3+-doped are 0.025, 0.025, and 0.02 mol, respectively, and Tb3+-doped samples has high quenching concentration. |
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| Keywords: | materials phosphor high temperature solid-state reaction phosphate substrate white LED |
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