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Ta2O5介质膜性能对液体钽电容器性能的影响
引用本文:陆胜,刘仲娥,梁正书,刘凌,阴学清.Ta2O5介质膜性能对液体钽电容器性能的影响[J].压电与声光,2006,28(4):475-477,480.
作者姓名:陆胜  刘仲娥  梁正书  刘凌  阴学清
作者单位:1. 天津大学,电子信息工程学院,天津,300072
2. 国营第4326厂,贵州,贵阳,550018
基金项目:国家自然科学基金资助项目(60371028)
摘    要:叙述了钽电解电容器阳极Ta2O5介质膜的形成过程,分析了电解液闪火与氧化膜击穿的微观过程。利用扫描电子显微镜(SEM)分析了阳极氧化后及产品失效后阳极钽芯表面介质膜的微观结构,并对液钽电容器失效机理进行了探讨。结果表明,介质膜内杂质或缺陷处O2-放电产生的电子发射是电解液闪火和氧化膜击穿的前驱点;在高电场或高温度的作用下,介质膜的场致晶化和热致晶化是液体钽电解电容器失效的主要模式。

关 键 词:Ta2O5介质膜  液体钽电解电容器  失效机理
文章编号:1004-2474(2006)04-0475-03
收稿时间:2005-03-07
修稿时间:2005-03-07

Influence of Capability of Ta2O5 Dielectric Film on Performance of Wet Tantalum Electrolytic Capacitor
LU Sheng,LIU Zhong-e,LIANG Zheng-shu,LIU Ling,YING Xue-qing.Influence of Capability of Ta2O5 Dielectric Film on Performance of Wet Tantalum Electrolytic Capacitor[J].Piezoelectrics & Acoustooptics,2006,28(4):475-477,480.
Authors:LU Sheng  LIU Zhong-e  LIANG Zheng-shu  LIU Ling  YING Xue-qing
Affiliation:1. School of Electronic Information Engineering, Tianjin University, Tianjin 300072 ,China; 2. State Enterprise 4326 ,Guiyang 550018,China
Abstract:Forming process of anodic Ta_2O_5 dielectric film of wet tantalum electrolytic capacitors was analyzed,and the microprocess of electrolyte sparking and the oxide film breakdown were studied.The surface microstructure of anodic tantalum core was analyzed by scanning electron microscope(SEM),and then analyzed the failure mechanism of wet tantalum capacitor.The results shows that the electron emission caused by discharge of O~(2-)is the prelude of oxide film breakdown and electrolyte sparking,the crystallization of Ta_2O_5 dielectric film caused by high electric field and high temperature are the mostly failure mechanism.
Keywords:Ta_2O_5 dielectric film  wet tantalum electrolytic capacitor  failure mechanism
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