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Yb3+掺杂锌锗碲酸盐玻璃的热分析、光谱和激光性质
引用本文:汪国年,戴世勋,张军杰,胡丽丽,姜中宏. Yb3+掺杂锌锗碲酸盐玻璃的热分析、光谱和激光性质[J]. 中国激光, 2005, 32(3): 65-369
作者姓名:汪国年  戴世勋  张军杰  胡丽丽  姜中宏
作者单位:中国科学院上海光学精密机械研究所,上海,201800
基金项目:国家自然科学基金(60207006),上海青年科技启明星项目(04QMX1448)资助项目.
摘    要:设计了组成为0.70TeO2-(0.20-x)ZnO-xGeO2—0.05La2O3-0.025K2O-0.025Na2O-0.01Yb2O3(摩尔分数x=0,0.05,0.10,0.15和0.20)的碲酸盐激光玻璃,测试了热学性质、吸收光谱、荧光光谱和荧光寿命。计算了Yb^3 离子的吸收截面、受激发射截面、荧光有效线宽等参数。结果表明,组成为0.70TeO2-0.20GeO2-0.05La2O3-0.025K2O-0.025Na2O的玻璃具有优于著名的碲锌钠(TZN)玻璃的热稳定性,高的受激发射截面(1.23pm^2)。长的荧光寿命(0.92ms)和宽的荧光有效线宽(77nm)。通过激光性能评价。最小抽运强度为0.98kW/cm^2,表明掺Yb^3 组份的碲酸盐玻璃是实现高能短脉冲可调谐激光器的理想增益介质。

关 键 词:材料 碲酸盐玻璃 光谱性质 经典方程 Yb^3+离子
收稿时间:2003-12-23

Thermal, Spectra and Laser Properties of Yb:Zinc-Germanium-Tellurite Glasses for Laser
WANG Guo-nian,DAI Shi-xun,ZHANG Jun-jie,HU Li-li,JIANG Zhong-hong. Thermal, Spectra and Laser Properties of Yb:Zinc-Germanium-Tellurite Glasses for Laser[J]. Chinese Journal of Lasers, 2005, 32(3): 65-369
Authors:WANG Guo-nian  DAI Shi-xun  ZHANG Jun-jie  HU Li-li  JIANG Zhong-hong
Abstract:A series of new multi-component glasses of 0.70TeO2-(0.20-x)ZnO-xGeO2-0.05La2O3-0.025K2O-0.025Na2O-0.01Yb2O3 (mole fraction x=0, 0.05, 0.10, 0.15, 0.20) were presented. Thermal stability of the system, spectra and laser properties of Yb3+ ions were measured. The result shows that the composition glass of x=0.20 has good thermal stability, large stimulated emission cross-section of 1.23 pm2 for the 2F5/2→2F7/2 transition, longer fluorescence lifetime of 0.92 ms, broad fluorescence effective linewidth of 77 nm and minimize pump intensity of 0.98 kW/cm2. Evaluated from the good potential laser parameters, it is desirable for high-average power and short pulse tunable laser.
Keywords:materials  tellurite glass  spectroscopic property  empirical equation  Yb3+ ions
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