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锡阳极泥锡锑分离硫化挥发工艺试验研究
引用本文:尹久发,张启旺,张敏,卢红波. 锡阳极泥锡锑分离硫化挥发工艺试验研究[J]. 矿冶, 2012, 21(4): 58-62
作者姓名:尹久发  张启旺  张敏  卢红波
作者单位:1. 云南锡业集团(控股)有限责任公司研究设计院,云南个旧66100
2. 昆明理工大学冶金与能源工程学院,真空冶金国家工程实验室,昆明650093
基金项目:云南锡业集团(控股)公司一类科研项目
摘    要:研究了锡阳极泥锡锑分离硫化挥发过程,考察硫化铁加入量、反应时间、焙烧反应温度对试验结果的影响。在硫化铁与锡阳极泥比1∶4,反应温度1050℃,反应时间2 h的试验条件下,锡阳极泥锡锑有价金属分离率达90%以上。实现了锡阳极泥中锡锑等高价值金属有效综合利用,开发了火法处理锡阳极泥锡锑分离新工艺。

关 键 词:锡阳极泥  锡锑分离  硫化挥发工艺
收稿时间:2012-03-26
修稿时间:2012-08-21

TIN ANODE MUD TIN AND ANTIMONYSEPARATED SULFIDE VOLATILIZATION PROCESS TEST
Yin Jiu F,ZHANG Qi -wang,ZHANG- min and LU Hong-bo. TIN ANODE MUD TIN AND ANTIMONYSEPARATED SULFIDE VOLATILIZATION PROCESS TEST[J]. Mining & Metallurgy, 2012, 21(4): 58-62
Authors:Yin Jiu F  ZHANG Qi -wang  ZHANG- min  LU Hong-bo
Affiliation:1.Institute of Research and Design,Yunnan Tin Group(Holdings) Limited Liability Company,Gejiu 661000,Yunnan,China; 2 National Engineering Laboratory of Vacuum Metallurgy,Kunming University of Science and Technology,Kunming 650093,China)
Abstract:Sulfide volatilization process of tin and antimony separation in tin anode mud is studied and the effect of iron sulfide dosage,reaction time,calcination reaction temperature on the test results is examined.Under the situation of iron sulfide and tin anode mud ratio 1∶4,reaction temperature of 1050 ℃,and reaction time 2 hours,the tin anode mud tin-antimony metallic element separation rate reaches above 90%,which realizes the effective comprehensive utilization of tin,antimony and other high value metals and is a kind of innovative pyrometallurgical processing of tin and antimony separation technology for tin anode mud.
Keywords:Tin anode mud   Tin and antimony separation   Sulfide volatilization process
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