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有色金属工业含砷污染物处理研究进展
引用本文:王长印,李旻廷,魏昶,邓志敢,李兴彬,刘慧杨,雷佛光.有色金属工业含砷污染物处理研究进展[J].矿冶,2020,29(1):86-93.
作者姓名:王长印  李旻廷  魏昶  邓志敢  李兴彬  刘慧杨  雷佛光
作者单位:昆明理工大学冶金与能源工程学院,昆明650093;昆明理工大学冶金与能源工程学院,昆明650093;昆明理工大学冶金与能源工程学院,昆明650093;昆明理工大学冶金与能源工程学院,昆明650093;昆明理工大学冶金与能源工程学院,昆明650093;昆明理工大学冶金与能源工程学院,昆明650093;昆明理工大学冶金与能源工程学院,昆明650093
基金项目:国家自然科学基金项目(面上项目,重点项目,重大项目)
摘    要:综述了有色金属工业砷污染物的来源及其无害化处理的方法,分析了包封固砷(水泥固化和玻璃固化)和矿物固砷(钙盐、铝盐、镁盐、硫化沉淀法)的优缺点和局限性,重点对将砷以臭葱石形式进行安全处理的合成方法和浸出稳定性的研究现状进行阐述。分析表明,晶态臭葱石合成是将砷以臭葱石形式进行安全处置的基础,稳定性是关键,进一步降低溶液过饱和度以实现大尺寸、高稳定性臭葱石的合成是发展方向。

关 键 词:含砷污染物  包封固砷  矿物固砷  臭葱石
收稿时间:2019/8/5 0:00:00
修稿时间:2019/9/11 0:00:00

Progress in treatment of arsenic-containing contaminant in non-ferrous metals industry
Wang Changyin,Li Minting,Wei Chang,Deng Zhigan,Li Xingbin,Liu huiyang and Lei fuguang.Progress in treatment of arsenic-containing contaminant in non-ferrous metals industry[J].Mining & Metallurgy,2020,29(1):86-93.
Authors:Wang Changyin  Li Minting  Wei Chang  Deng Zhigan  Li Xingbin  Liu huiyang and Lei fuguang
Affiliation:Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Yunnan,650093;china
Abstract:This paper reviews the sources of arsenic-containing contaminant in non-ferrous metals industry and their harmless treatment methods, and analyzes the advantages of encapsulated arsenic (cement curing and glass curing) and mineral solid arsenic (calcium, aluminum, magnesium, and sulfide precipitation methods). Disadvantages and limitations, focusing on the research status of synthetic methods and leaching stability for safe treatment of arsenic in the form of scorodite. The analysis shows that the crystalline scorodite synthesis is the basis for the safe disposal of arsenic in the form of scorodite. Stability is the key. Further reducing the supersaturation of the solution to achieve the synthesis of large-size and high-stability scorodite is the development direction.
Keywords:Arsenic-containing contaminant  encapsulated arsenic  mineral solid arsenic  scorodite
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