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微晶纤维素改性磷建筑石膏性能研究
引用本文:廖仕雄,郭荣鑫,赵志曼,成俊辰,全思臣,刘卓,王存,张芷绮.微晶纤维素改性磷建筑石膏性能研究[J].非金属矿,2021(2):92-94,98.
作者姓名:廖仕雄  郭荣鑫  赵志曼  成俊辰  全思臣  刘卓  王存  张芷绮
作者单位:昆明理工大学建筑工程学院;昆明理工大学云南省土木工程防灾重点实验室;云南凝创环保科技有限公司
基金项目:国家自然科学基金(51662022);昆明理工大学分析测试基金(2019M20182210057)。
摘    要:以微晶纤维素为改性材料,探究微晶纤维素在不同掺量下对磷建筑石膏力学性能及耐水性能影响,并对其水化产物及微观形貌进行分析。结果表明,微晶纤维素掺量为0.09%时,磷建筑石膏基复合材料的绝干抗折强度、绝干抗压强度、软化系数最优,分别为4.75 MPa、17.65 MPa、0.61,较空白组分别增加36.5%、31.2%、29.8%,吸水率达到最优值18.36%,较空白组降低18.62%。适量微晶纤维素掺入到磷建筑石膏中,能促进磷建筑石膏水化及填充二水石膏晶体的内部空隙,使磷建筑石膏内部结构更加密实,提高磷建筑石膏的力学性能及耐水性。

关 键 词:微晶纤维素  磷建筑石膏  强度  耐水性  微观形貌

Study on the Performance of Microcrystalline Cellulose Modified Phosphorus Building Gypsum
Liao Shixiong,Guo Rongxin,Zhao Zhiman,Cheng Junchen,Quan Sichen,Liu Zhuo,Wang Cun,Zhang Zhiqi.Study on the Performance of Microcrystalline Cellulose Modified Phosphorus Building Gypsum[J].Non-metallic Mines,2021(2):92-94,98.
Authors:Liao Shixiong  Guo Rongxin  Zhao Zhiman  Cheng Junchen  Quan Sichen  Liu Zhuo  Wang Cun  Zhang Zhiqi
Affiliation:(College of Architectural Engineering,Kunming University of Science and Technology,Kunming,Yunnan 650500;Yunnan Key Laboratory of Civil Engineering Disaster Prevention,Kunming University of Science and Technology,Kunming,Yunnan 650500;Yunnan Cohesive Environmental Protection Technology Company Limited,Kunming,Yunnan 650500)
Abstract:Taking microcrystalline cellulose as modified material,the influence of microcrystalline cellulose dosage on the mechanical properties and water resistance of phosphorousous building gypsum was investigated,and the hydration products and micro-morphology were analyzed.The results show that when the microcrystalline cellulose content is 0.09%,the absolute dry flexural strength and compressive strength,softening coefficient and water absorption of the composite are 4.75 MPa,17.65 MPa,0.61 and 18.36%,respectively,compared with blank group,the absolute dry flexural strenghth and compressive strengh,softening coefficient increased by 36.5%,31.2%and 29.8%,respectively,its water absorption rate decreased by 18.62%.An appropriate amount of microcrystalline cellulose can promote the hydration of phosphorous building gypsum and fill the internal gap of dihydrate gypsum crystal,make the internal structure of phosphorous building gypsum more dense,improve the mechanical properties and water resistance of phosphorous building gypsum.
Keywords:microcrystalline cellulose  phosphorous building gypsum  strength  water resistance  microstructure
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