| 羟铂酸的制备与表征 |
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| 引用本文： | 张向军,卢世刚,李文忠.羟铂酸的制备与表征[J].稀有金属,2005,29(3):307-310. |
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| 作者姓名： | 张向军 卢世刚 李文忠 |
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| 作者单位： | 北京有色金属研究总院矿物冶金与材料研究所,北京,100088 |
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| 摘 要： | 采用水解法制备了羟铂酸(H2Pt(OH)6)，通过化学分析、XRD、TG／DSC、XPS、FTIR等技术对羟铂酸的组成和结构进行了分析和表征。通过化学分析检测所制备的化合物中铂的含量为65．07％，与H2Pt(OH)6中的铂的理论含量65．22％相比，两者相符较好，结合XRD衍射，表明所制备的化合物为H2Pt(OH)6，属单斜晶系；通过TG／DSC，XPS，FTIR等检测技术，推断H2Pt(OH)6为Pt(Ⅳ)与配位水和羟基配位基团形成的络合物，具有八面体空间结构。
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| 关 键 词： | 羟铂酸 配合物 制备 表征 |
| 文章编号： | 0258-7076(2005)03-0307-04 |
Preparation and Characterization of H2Pt(OH)6 |
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| Zhang Xiangjun,Lu Shigang,Li Wenzhong.Preparation and Characterization of H2Pt(OH)6[J].Chinese Journal of Rare Metals,2005,29(3):307-310. |
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| Authors: | Zhang Xiangjun Lu Shigang Li Wenzhong |
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| Affiliation: | Zhang Xiangjun~*,Lu Shigang,Li Wenzhong |
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| Abstract: | H_2Pt(OH)_6 was prepared by hydrolysis method, and characterized by chemical analyses, XRD, TG/DSC, XPS and FTIR. The measured contents of Pt existing in the H_2Pt(OH)_6 is equal to 65.07%, by means of chemical analyses, which agreed with the theoretical calculation (65.22%). XRD result shows that H_2Pt(OH)_6 crystal is in monoclinic system with C2/c space group. The results of the TG/DSC, XPS and FTIR test indicate that H_2Pt(OH)_6 is a octahedron-structured complex involving H_2O and OH ligands. |
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| Keywords: | H_2Pt(OH)_6 complex preparation characterization |
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