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复杂黄金废水深度净化与脱盐回用技术研究与实践
引用本文:石绍渊,王军强,王永春,王国栋,张曼曼,孙峙.复杂黄金废水深度净化与脱盐回用技术研究与实践[J].黄金科学技术,2018,26(4):535-542.
作者姓名:石绍渊  王军强  王永春  王国栋  张曼曼  孙峙
作者单位:1. 北京市过程污染控制工程研究中心,中国科学院过程工程研究所,北京 100190;2.灵宝黄金集团股份有限公司,河南 灵宝 472500;3.郑州中科新兴产业技术研究院,河南 郑州 450000
基金项目:国家自然科学基金项目“基于表面复合改性提高阴离子交换膜抗污染性能及机理研究”((编号:51878645));国家重点研发计划“LED照明产品全链条绿色回收与绿色设计技术研究”((编号:2017YFB0403305));河南省科技开放课题“黄金冶炼废水综合治理与回用关键技术研发”((编号:172106000076));“十二五”水体污染控制与治理科技重大专项基金“饮马河流域中游玉米深加工园区水污染全过程控制技术集成与示范”((编号:2014ZX07201-011)联合资助)
摘    要:针对黄金湿法冶炼废水存在含盐量高,多种重金属、氨氮、氰化物和COD等超标造成环境污染严重,以及现有废水处理技术无法实现达标排放的问题,研发出一系列适用于黄金湿法冶炼废水深度处理与脱盐回用关键技术,包括污酸除杂及资源化、有价金属回收与重金属深度脱除、疏水膜回收氰、高级氧化去除有机物和电渗析脱盐等,进行多污染物协同控制及资源化的关键技术集成,建立黄金湿法冶炼废水多污染物协同控制及资源化工艺包,形成成套化技术与装备,并通过现场中试验证技术可行性,推动了该技术的产业化应用,可实现黄金湿法冶炼废水深度处理与近零排放。

关 键 词:黄金湿法冶炼  废水深度处理  污酸资源化  氰回收  高级氧化  电渗析脱盐  近零排放  
收稿时间:2018-04-25
修稿时间:2018-07-16

Research and Practice of Deep Purification and Desalination Reuse Technology for Complex Gold Wastewater
Shaoyuan SHI,Junqiang WANG,Yongchun WANG,Guodong WANG,Manman ZHANG,Zhi SUN.Research and Practice of Deep Purification and Desalination Reuse Technology for Complex Gold Wastewater[J].Gold Science and Technololgy,2018,26(4):535-542.
Authors:Shaoyuan SHI  Junqiang WANG  Yongchun WANG  Guodong WANG  Manman ZHANG  Zhi SUN
Affiliation:1. Beijing Engineering Research Center of Process Pollution Control,Division of Environment Technology and Engi-neering,Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,;2.Lingbao Gold Group Co.,Ltd.,Lingbao 472500,Henan,China;3.Zhengzhou Institute of Emerging Industrial Technology,Zhengzhou 450000,Henan,China
Abstract:The serious environmental pollution is caused by gold hydrometallurgy wastewater due to containing large amount of inorganic salts,various heavy metals,ammonia nitrogen,cyanide and COD,etc.,but the target discharge of wastewater cannot be achieved by the present treatment technologies.A series of key technologies for advanced treatment and desalination reuse of gold hydrometallurgical wastewater have been developed,including waste acid purification and resource,valuable metal recovery and heavy metal removal,cyanide recovery by hydrophobic membrane,organic matter removal by advanced oxidation,electrodialysis desalination,etc.The key technologies were integrated for collaborative control and resource utilization of multiple pollutants,to establish the engineering package of multi pollutant collaborative control and resource for gold hydrometallurgy wastewater and to form a complete technology and equipment.The application feasibility of related technologies was verified by field test.The industrial application of the technology has been promoted for achieving the goal of advanced treatment and near zero discharge of gold hydrometallurgical wastewater.
Keywords:gold hydrometallurgy  wastewater advanced treatment  waste acid resource  cyanide recovery  advanced oxidation  electrodialysis desalination  near zero-emissions  
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