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Investigation on the icosahedral quasicrystal phase in Mg70.8Zn28Nd1.2 alloy
Authors:ZHANG Jinshan  YAN Jie  HAN Fuyin  LIANG Wei  XU Chunxiang  ZHOU Cuilan
Affiliation:College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Abstract:Mg70.8Zn28Nd1.2 (mole fraction) alloy containing icosahedral quasicrystal phase (I-phase) was prepared under conventional metal casting conditions. The microstructure, phase constitution and phase structure of the alloy were investigated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS) and transmission electron microscopy (TEM). The re-sults showed that the spherical phase in MgT70.8Zn28Nd1.2 alloy was a simple icosahedral quasicrystal with stoichiometric composition of Mg40Zn55Nd5 and quasi-lattice of 0.525 nm. In this research, the as-cast microstructure of Mg70.8Zn28Nd1.2 alloy mainly consisted of Mg40Zn55Nd5 icosahedral quasicrystal phase and Mg7Zn3 columnar crystal matrix. In the growing process of Mg40Zn55Nd5 icosahedral qua-sicrystal phase, the growth morphology mainly depended on interface energy, adsorption effect of Nd and cooling rate.
Keywords:Mg-Zn-Nd  icosahedral quasicrystal phase  microstructure  growth morphology  adsorption  rare earths
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