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Photoluminescence of SrGdGa_3O_7∶RE (RE=Ce~(3 ), Pr~(3 ), Tb~(3 )) under VUV-UV Excitation
引用本文:张新民,梁宏斌,叶祥,陶冶,苏锵.Photoluminescence of SrGdGa_3O_7∶RE (RE=Ce~(3 ), Pr~(3 ), Tb~(3 )) under VUV-UV Excitation[J].中国稀土学报(英文版),2005,23(3).
作者姓名:张新民  梁宏斌  叶祥  陶冶  苏锵
作者单位:State Key Laboratory of Optoelectronic Materials and Technologies,School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China,School of Chemical Science,South China University of Technology,Guangzhou 510641,China,State Key Laboratory of Optoelectronic Materials and Technologies,School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China,State Key Laboratory of Optoelectronic Materials and Technologies,School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China,Guangzhou Research Institute of Non-Ferrous,Guangzhou 510651,China,Laboratory of Beijing Synchrotron Radiation,Institute of High Energy Physics,Chinese Academy of Science,Beijing 100039,China,State Key Laboratory of Optoelectronic Materials and Technologies,School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China
基金项目:theNationalNaturalScienceFoundationofChina (2 0 1710 46)andNaturalScienceFoundationofGuangdongProvinc (0 0 12 77)andDoctorialTrainingBaseFoundationofMinistryofEducationofChina (2 0 0 2 0 5 5 80 3 4)
摘    要:SrGdGa3 O7belongstothelargefamilieswhosegeneralchemicalformulaisAMM′3 O7(A =Ca ,Sr ,Ba ;M =La ,Gd ,Y ;M′ =Al,Ga) .Thesecom poundshavemelilitestructure .Structuralinvestiga tionsindicatethatSrGdGa3 O7formstetragonalcrystalswithspacegroupP 4 2 1m .Theunit…

关 键 词:phosphor  SrGdGa3O7∶Ce3    Pr3    Tb3    luminescence  vacuum  ultraviolet  (VUV)  rare  earths

Photoluminescence of SrGdGa3O7∶RE (RE=Ce3+, Pr3+, Tb3+) under VUV-UV Excitation
Zhang Xinmin,Liang Hongbin,YE Xiang,Tao Ye,Su Qiang.Photoluminescence of SrGdGa3O7∶RE (RE=Ce3+, Pr3+, Tb3+) under VUV-UV Excitation[J].Journal of Rare Earths,2005,23(3).
Authors:Zhang Xinmin  Liang Hongbin  YE Xiang  Tao Ye  Su Qiang
Abstract:SrGdGa3O7:RE (RE=Ce3+, Pr3+, Tb3+) were prepared by traditional solid-state reaction and their luminescence properties in the range of VUV-Vis were investigated. The two broad bands situated at about 177 and 217 nm in excitation spectra are attributed to the host lattices absorption, and they have no considerable change when doped different rare earth ions. The f-d transitions of Pr3+ and Tb3+ calculated by the formula gathered by Dorenbos were compared to the experimental results. The excitation spectra also show the sharp Gd3+ excitation line at about 274 nm pointing to an efficient energy transfer from Gd3+ to Pr3+ and Tb3+. All of the emission spectra present the characteristic emissions of rare earth ions when excited by VUV and UV.
Keywords:phosphor  luminescence  vacuum ultraviolet (VUV)  rare earths
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