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含可聚合乳化剂的苯丙乳液合成及其在复膜胶中的应用
引用本文:黄增芳,马军现.含可聚合乳化剂的苯丙乳液合成及其在复膜胶中的应用[J].中国胶粘剂,2011,20(8).
作者姓名:黄增芳  马军现
作者单位:电子科技大学中山学院化学与生物工程学院,广东中山,528402
基金项目:广东省自然科学基金项目(9452840301003542); 中山市科技计划项目(20092A203); 电子科技大学中山学院科研启动基金项目(408YKQ04)资助
摘    要:以十二烷基苯磺酸钠(SDBS)为阴离子型乳化剂、辛烷基苯酚聚氧乙烯醚-10(OP-10)为非离子型乳化剂、烯丙氧基壬基苯氧基丙醇聚氧乙烯醚硫酸铵(SE-10)为可聚合型乳化剂、苯乙烯(St)为硬单体、丙烯酸丁酯(BA)为软单体和丙烯酸(AA)为功能单体等,在复合乳化剂OP-10/SDBS、OP-10/SE-10作用下分别制备了纸/塑、塑/塑复膜胶。结果表明:SE-10的乳化效果优于SDBS,前者可有效提高复膜胶的初粘力和剥离强度,并可有效降低乳胶粒的平均粒径;以OP-10/SE-10作为复合乳化剂,当w(AA)=8.3%时,复膜胶的初粘力和剥离强度均达到最大值,并且其热稳定性相对较好。

关 键 词:苯丙乳液  可聚合乳化剂  复膜胶

Synthesis of styrene-acrylate emulsion with polymerizable emulsifier and its application in laminating adhesive
Huang Zengfang,Ma Junxian.Synthesis of styrene-acrylate emulsion with polymerizable emulsifier and its application in laminating adhesive[J].China Adhesives,2011,20(8).
Authors:Huang Zengfang  Ma Junxian
Affiliation:Huang Zengfang,Ma Junxian(College of Chemistry and Biology Engineering,Zhongshan Institute,Electronic University of Science & Technology,Zhongshan 528402,China)
Abstract:With sodium dodecyl benzene sulfonate(SDBS) as anionic emulsifier,octyl phenol ethoxylates-10(OP-10) as nonionic emulsifier,SE-10 as polymerizable emulsifier,styrene(St) as hard monomer,butyl acrylate(BA) as soft monomer and acrylic acid(AA) as functional monomer,the laminating adhesives for paper/plastic and plastic/plastic were prepared by OP-10/SDBS or OP-10/SE-10 composite emulsifier.The results showed that the emulsification effect of SE-10 was better than that of SDBS,the former could effectively impr...
Keywords:styrene-acrylate emulsion  polymerizable emulsifier  laminating adhesive  
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