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乳液型纸塑复膜胶的研制
引用本文:梁文庆,唐宏科,孙夏.乳液型纸塑复膜胶的研制[J].中国胶粘剂,2009,18(11).
作者姓名:梁文庆  唐宏科  孙夏
作者单位:1. 教育部轻化工助剂化学与技术重点实验室,陕西科技大学,陕西西安710021
2. 山东贝斯特化工有限公司,山东东营,257300
摘    要:以丙烯酸丁酯(BA)和丙烯酸异辛酯(2-EHA)为软单体、醋酸乙烯(VAc)为硬单体和丙烯酸(AA)为功能单体,采用预乳化种子乳液聚合法成功合成了性能优良的醋丙乳液纸塑复膜胶。着重讨论了单体的选择、软硬单体配比、引发剂、乳化剂以及功能单体的用量等因素对乳液性能的影响。研究结果表明:当m(软单体):m(硬单体)=45:50~50:45、w(引发剂)≈0.6%、w(乳化剂)=3.0%和w(功能单体)=6%时,乳液具有较好的纸塑粘接性能。

关 键 词:丙烯酸酯  乳液  醋酸乙烯  乳液聚合  纸塑复合  胶粘剂

Study on emulsion-type adhesive for paper-plastic lamination
LIANG Wen-qing,TANG Hong-ke,SUN Xia.Study on emulsion-type adhesive for paper-plastic lamination[J].China Adhesives,2009,18(11).
Authors:LIANG Wen-qing  TANG Hong-ke  SUN Xia
Affiliation:LIANG Wen-qing1,TANG Hong-ke1,SUN Xia2(1.Key laboratory of Auxiliary Chemistry & Technology for Chemical Industry,Ministry of Education,Shaanxi University of Science & Technology,Xi'an 710021,China,2.Shandong Best Chemical Industry Co.,Ltd.,Dongying 257300,China)
Abstract:With butyl acrylate(BA) and 2-ethylhexyl acrylate(2-EHA) as soft monomers,vinyl acetate(VAc) as hard monomer and acrylic acid(AA) as functional monomer,so a vinyl acetate-acrylate emulsion adhesive with excellent performance for paper-plastic laminating was prepared by seeding pre-emulsion polymerization.The influences of monomer choice,monomers ratio of soft to hard,initiator content,emulsifier contents,functional monomer contents and other factors were emphatically discussed on emulsion performance.The re...
Keywords:acrylate  emulsion  VAc  emulsion polymerization  paper-plastic lamination  adhesive  
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