Temperature and processing effects on lithium ion conductivity of solution-deposited lithium zirconium phosphate (LiZr2P3O12) thin films |
| |
Authors: | Ian A Brummel Daniel E Drury Andrew R Kitahara Farid El Gabaly Jon F Ihlefeld |
| |
Affiliation: | 1. Department of Materials Science and Engineering, University of Virginia, Charlottesville, VA, USA;2. Sandia National Laboratories, Albuquerque, NM, USA;3. Sandia National Laboratories, Livermore, CA, USA |
| |
Abstract: | Lithium zirconium phosphate (LiZr2P3O12) thin films have been prepared on platinized silicon substrates via a chemical solution deposition approach with processing temperatures between 700°C and 775°C. Films that were subject to a single high-temperature anneal were found to crystallize at temperatures above 725°C. Crystallization was observed in films annealed after each deposited layer at 700°C and above. In both cases, grain size was found to increase with annealing temperature. Ion conductivity was found to increase with annealing temperature in singly annealed films. In per-layer annealed films ion conductivity was found to initially increase then decrease with increasing annealing temperature. A maximum ion conductivity of 1.6 × 10?6 S/cm was observed for the singly annealed 775°C condition, while a maximum ion conductivity of 5.8 × 10?7 S/cm was observed for the 725°C per-layer annealed condition. These results are consistent with an increasing influence of cross-plane, internal interface resistance and vapor phase carrier loss in the per-layer annealed samples. This work demonstrates that post-deposition processing methods can strongly affect the ion conducting properties of LiZr2P3O12 thin films. |
| |
Keywords: | ionic conductivity processing sol-gel thin films |
|
|