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A New Aluminum Coordination Site in Si-C-Al-N-(O) Ceramics
Authors:Xudong Li  Mohan J Edirisinghe
Affiliation:Department of Materials, Queen Mary, University of London, Mile End Road, London E1 4NS, United Kingdom
Abstract:A variety of Si-C-Al-N-(O) ceramics with different AlN and SiC contents were prepared by pyrolysis of Si-Al-C-O precursors at 1700°C in nitrogen. In those ceramics containing small amounts of aluminum, a new 27Al MAS NMR peak at 134.3 ppm was found. The existence of this peak is discussed in relation to recent findings in aluminum-containing complex ceramic systems.
Keywords:aluminum  aluminum nitride  pyrolysis
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