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6-羟基-2,4-(4′-羧基苯氧基)均三嗪与Zn(Ⅱ)配合物的合成及晶体的培养
引用本文:李立军,荣继武,刘丽英,杨东杰.6-羟基-2,4-(4′-羧基苯氧基)均三嗪与Zn(Ⅱ)配合物的合成及晶体的培养[J].广东化工,2010,37(3):117-117,138.
作者姓名:李立军  荣继武  刘丽英  杨东杰
作者单位:河北大学,化学与环境科学学院,河北,保定,071002
摘    要:6-羟基-2,4-二(4’-羧基苯氧基)均三噱与六水合硝酸锌在一定条件下可以形成配合物。文章重点介绍该配体与金属盐的摩尔比为1:2时,用水热法培养出6-羟基-2,4-二(4’-羧基苯氧基)均三嗪和六水合硝酸镑所形成的白色粒状单晶。适宜温度为120℃,反应时间为7d。

关 键 词:6-羟基-2  4-二(4'-羧基苯氧基)均兰礤  ZaCl2·6H2O  水热法  单鼎

Synthesis of 2,4-Bis(4-carboxyl phenoxyl)-6-hydroxyltriazine with Zinc(Ⅱ)and Cultivation of Crystal
Li Lijun,Rong Jiwu,Liu Liying,Yang Dongjie.Synthesis of 2,4-Bis(4-carboxyl phenoxyl)-6-hydroxyltriazine with Zinc(Ⅱ)and Cultivation of Crystal[J].Guangdong Chemical Industry,2010,37(3):117-117,138.
Authors:Li Lijun  Rong Jiwu  Liu Liying  Yang Dongjie
Affiliation:(College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China)
Abstract:2,4-Bis(4-carboxyl phenoxyl)-6-hydroxyltriazine and Zinc nitrate hexahydrate can form coordination complexes under the certain condition. The paper mainly introduced the white grain-shaped single crystals of coordination complex with 2,4-Bis(4-carboxyl phenoxyl)-6-hydroxyltriazine and Zinc nitrate hexahydrate can be cultivated by Hydrothermal synthesis when ligand and metallic salts were mixed together according to 1 : 2 of mole. The appropriate temperature was 120℃.
Keywords:2  4-Bis(4-carboxylphenoxyl)-6-hydroxyltriazine  zincnitratehexahydrate  hydrothermalsynthesis  single crystal
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