Study on synthesis and electrochemical properties of novel ferrocene-based compounds and their applications in anion recognition |
| |
| Authors: | Liang Ma Qiaohua Tan Haojie Yu Jia Huo Zhenni Ma Huarong Hu Zhefu Chen |
| |
| Affiliation: | State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China |
| |
| Abstract: | Two novel ferrocene-based compounds glycidyl ester of ferrocene carboxylate (GEFC) and 1,3-diferrocenecarboxylic acid diacylglycerol (DFCDG) were synthesized and characterized by 1H NMR and mass spectrum. The influence of some factors, namely, solvent type, potential scan rate, electrolyte concentration and Fe] unit concentration, on the electrochemical behaviors of two novel ferrocene-based compounds was investigated, and the mechanism of the electrode processes was studied. Finally, two compounds were applied to sense the H2PO4− by cyclic voltammetry (CV) method and it was found that the DFCDG with a symmetric structure which was synthesized through ring opening reaction of ferrocene carboxylate and GEFC showed stronger interaction with the H2PO4− than GEFC. |
| |
| Keywords: | Ferrocene Ester Epoxy compound Electrochemical behaviors Anion recognition |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
