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Charge cycling and impedance characterization of a polyphosphazene solid polymer electrolyte-manganese(IV) oxide intercalation cathode
Authors:Lei GaoDigby D. Macdonald  Mirna Urquidi-MacdonaldDavid L. Olmeijer  Harry R. Allcock
Affiliation:a Center for Electrochemical Science and Technology, Pennsylvania State University, 201 Steidle Building, University Park, PA 16802, USA
b Department of Engineering Science and Mechanics, Pennsylvania State University, 225 Hammond Building, University Park, PA 16802, USA
c Department of Chemistry, The Pennsylvania State University, 152 Davey Laboratory, University Park, PA 16802, USA
Abstract:The compatibility of polyphosphazene (PPZ) polymer electrolytes with MnO2/C/SPE intercalation cathodes (IC) was investigated. Three-layered laminates of a phosphazene-based solid polymer electrolyte (SPE) film sandwiched between two MnO2-based ICs (one preloaded with lithium) were constructed. The cathodes were fabricated by either solvent casting or compression techniques. Two different crystal forms of manganese(IV) oxide—λ-MnO2 and γ-MnO2—were employed, together with methoxy ethoxy ethoxy PPZ (MEEP) SPE binder material. Carbon black was employed as the electronically conductive phase. One cathode in each laminate was prepared in the ‘chemically intercalated’ form by using LiMn2O4 in place of MnO2. The podand polymer, SMEP, which has better thin film mechanical properties than does MEEP, was complexed with lithium trifluoromethane sulfonate (Li triflate) and used as the SPE. Li+ ions were cycled galvanostatically between the two-ICs, through the phosphazene-based SPE layer. The performance of the cell was continuously monitored by electrochemical impedance spectroscopy (EIS) and by measuring the laminate thickness and voltage drop. The method of cathode fabrication (casting vs. pressing) was found to be the primary factor influencing the cycle life.
Keywords:Lithium batteries   Solid polymer electrolytes   Manganese dioxide   Intercalation cathode
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