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A ratiometric fluorescent sensor for zinc(II) with high selectivity
Authors:Huili Chen  Yanbo Wu  Yunfei Cheng  Hong Yang  Fuyou Li  Pin Yang  Chunhui Huang  
Affiliation:aInstitute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Education Ministry, Shanxi University, Taiyuan 030006, PR China;bDepartment of Chemistry, Laboratory of Advanced Materials, Fudan University, Shanghai 200433, PR China
Abstract:Spectroscopic studies revealed that the compound N,N′-di(quinoline-2-methylene) -1,2-phenylenediimine] (1) exhibited a rather high selectivity toward Zn2+ over other metal ions, even Cd2+. In acetonitrile, the red shift of fluorescent emission from 396 nm to 426 nm upon zinc binding is due to the formation of a 1:1 metal/ligand complex.
Keywords:Ratiometric  Fluorescence  Zn2+ sensor  Schiff base
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