Synthesis,structure and unprecedented self-assembly strategy of two six-membered Zn–organic macrocycles |
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| Affiliation: | 1. College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, Jiangsu Province 210009, PR China;2. State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China;1. Coordination Chemistry Laboratory, Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan;2. Department of Chemistry, McGill University, Montreal, QC H3A 2K6, Canada;3. Department of Biotechnology, Faculty of Biological Sciences, Quaid-i-Azam University, Islamabad 45320, Pakistan;4. Department of Energy Systems Engineering, Sukkur Institute of Business Administration, Sukkur, Pakistan;5. Department of Physics, University of Sargodha, Sargodha, Pakistan;1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China;2. Laboratory of National Defense for Radioactive Waste and Environmental Security, Southwest University of Science and Technology, Mianyang 621010, China;3. SPrAM, UMR CEA/CNRS/UJF-Grenoble 1, INAC, Grenoble F-38054, France;4. Université Joseph Fourier Grenoble I, Département de Chimie Moléculaire, UMR CNRS-5250, Institut de Chimie Moléculaire de Grenoble, FR CNRS-2607, BP 53, 38041 Grenoble Cedex 9, France |
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| Abstract: | Two novel cyclohexane-like metallamacrocycles ZnCH3COO(L)]6·solvent (1) and Zn(HNO3)(L)]6·solvent (2) (HL = 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine) have been synthesized under hydrothermal conditions and characterized by IR spectra, single crystal X-ray diffraction, PXRD analysis, thermogravimetric analysis. The X-ray single crystal diffraction indicates that the self-assembly of the metallamacrocycle generates a fused-ring network that is further assembled into a 3D structure with 1D suprachannels. In particular, a designed self-assembly strategy has been applied to achieving six-membered Zn–organic metallamacrocycles unprecedentedly. |
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