| 新型有机盐光引发剂的双光子聚合特性研究 |
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| 引用本文： | 王雨兰,陈卫强,董贤子,杜振霞,段宣明.新型有机盐光引发剂的双光子聚合特性研究[J].感光科学与光化学,2007,25(5):350-356. |
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| 作者姓名： | 王雨兰 陈卫强 董贤子 杜振霞 段宣明 |
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| 作者单位： | [1]北京化工大学化学系,北京100029 [2]中国科学院理化技术研究所,北京100080 |
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| 摘 要： | 本文运用激光微细加工技术，通过对不同浓度引发剂的甲基丙烯酸类树脂的聚合行为进行评价，研究了1-甲基-2-2-（9-戊基-咔唑-3-基）-乙烯基]-3，3-二甲基吲哚碘盐（Ⅰ）作为双光子光引发剂的聚合特性，结果表明该化合物在扫描速度为44μm／s时，双光子聚合阈值为139kJ／cm%2；当激光能量密度为286kJ／cm^2时，引发聚合的曝光时间阈值为0．7ms．实验结果为进一步作为双光子聚合三维结构的微细加工提供了可靠依据．
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| 关 键 词： | 有机盐 双光子聚合引发剂 聚合速率 光聚合阈值 |
| 文章编号： | 1000-3231（2007）05-0350-07 |
| 修稿时间： | 2007-03-07 |
Novel Organic Salts as Two-Photon Polymerization Photoinitiator: Synthesis and Properties |
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| WANG Yu-lan, CHEN Wei-qiang, DONG Xian-zi, DU Zhen-xia, DUAN Xuan-ming.Novel Organic Salts as Two-Photon Polymerization Photoinitiator: Synthesis and Properties[J].Photographic Science and Photochemistry,2007,25(5):350-356. |
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| Authors: | WANG Yu-lan CHEN Wei-qiang DONG Xian-zi DU Zhen-xia DUAN Xuan-ming |
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| Affiliation: | 1. Department of Chemistry, Beijing; University of Chemical Technology, Beijing 100029, P. R. China ; 2. Technical Institute of Chemistry and Physics, Chinese Academy of Sciences, Beijing 100080, P. R. China |
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| Abstract: | 2-2-(9-Pentyl-carbazol-3-yl)-vinyl]-1,3,3-trimethyl indolium iodide (I) was synthesized and its photophysical properties were investigated. The properties of two-photon induced polymerization for acrylate resin with compound I as the initiator were studied on laser power, scanning speed and initiator concentration. The results showed that the threshold laser energy for resin was 139 kJ/cm2 when 0.88% of I was used as initiator and the threshold exposure time was 0.7 ms when the laser energy was 286 kJ/cm2. |
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| Keywords: | organic salt two-photon polymerization initiator polymerization velocity threshold |
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