A comparative study of the catalytic decomposition of methanol on rhodium and nickel |
| |
| Authors: | J J Weimer G K Chuah G Abend N Kruse J H Block |
| |
| Affiliation: | (1) Fritz-Haber-Institut, Faradayweg 4-6, 1000 Berlin 33, West Germany;(2) Present address: Department of Chemistry, National University of Singapore, 0511 Kent Ridge, Singapore;(3) Present address: Technisch-Chemisches Laboratorium, ETH-Zentrum, Ch-8092 Zürich, Switzerland |
| |
| Abstract: | Pulsed field desorption mass spectrometry shows that decomposition of methanol on Rh and Ni occurs via step-wise hydrogen abstraction from an adsorbed methoxy. Contrary to previous suggestions, an alternative mechanism through adsorbed methyl was not observed on Ni for pressures up to 3×10–3 Pa and temperatures up to the desorption of CO. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
