| 半缩合低聚硅氧烷的合成及应用进展 |
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| 引用本文： | 胡建坤,;郁小芬,;陆阿定,;李娟,;龚淑玲. 半缩合低聚硅氧烷的合成及应用进展[J]. 有机硅材料及应用, 2014, 0(5): 382-387 |
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| 作者姓名： | 胡建坤, 郁小芬, 陆阿定, 李娟, 龚淑玲 |
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| 作者单位： | [1]浙江省海洋开发研究院,浙江舟山316021; [2]武汉大学化学与分子科学学院,武汉430072 |
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| 基金项目： | 国家自然科学基金（20772092）、国际科技合作专项基金（2011DFA41900）、湖北省杰出青年基金（2007AB13021）、舟山科技计划项目基金（2011C21058）. |
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| 摘 要： | 介绍了半缩合低聚硅氧烷（简称半缩合POSS）的类别，阐述了半缩合POSS的制备方法与途径，分析了各自的优缺点，并对半缩合POSS改性材料（包括改性环氧树脂、丙烯酸树脂、有机硅、聚氨酯等）的最新研究进展进行了描述，指出了半缩合POSS的发展与应用前景。
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| 关 键 词： | 半缩合 多面体 低聚倍半硅氧烷 硅烷 水解 剪角法 |
Development in the Synthesis and Applications of Incompletely Condensed Silsesquioxanes |
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| Affiliation: | HU Jian-kun, YU Xiao-fen, LU A-ding, LI Juan, GONG Shu-ling ( 1. Zhejiang Marine Development Research Institute, Zhoushan 316021, Zhejiang; 2. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, Hubei) |
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| Abstract: | The types and preparation methods of incompletely condensed silsesquioxanes （POSS）are introduced. Then the advantages and disadvantages of different POSS are analyzed. Moreover,the latest research progress on the incompletely condensed POSS modified materials （including modified epoxy,acrylic, silicone,polyurethane resin,etc. ）is described. Finally,the development and application prospect of the incompletely condensed POSS are also dsicussed. |
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| Keywords: | incompletely condensed polyhedral oligomeric silsesquioxanes silane hydrolysis shear angle |
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