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埃洛石对水性超薄膨胀型钢结构防火涂料防火性能的影响
引用本文:刘芳,孙令,唐万雄,蓝方维,贾德民,罗远芳.埃洛石对水性超薄膨胀型钢结构防火涂料防火性能的影响[J].涂料工业,2010,40(1).
作者姓名:刘芳  孙令  唐万雄  蓝方维  贾德民  罗远芳
作者单位:1. 华南理工大学材料科学与工程学院,广州,510641
2. 孙大化工科技有限公司,广东中山,528400
摘    要:以聚丙烯酸酯乳液为基体树脂,多聚磷酸铵、三聚氰胺、季戊四醇等为主阻燃剂,埃洛石纳米管(HNTs)为阻燃协效剂,制备了水性超薄膨胀型钢结构防火涂料,采用模拟大板燃烧法和锥形量热仪对其耐火性能进行了研究,并用扫描电镜观察了膨胀炭层的表面形貌。结果表明:HNTs对防火涂料的耐火性能影响显著,当阻燃体系中HNTs含量为10.86%时,HNTs与主阻燃剂之间有阻燃增效作用,所制备防火涂料的耐火时间为107 min,点燃时间为24 s,热释放速率峰值与点燃时间比为4.97,燃烧残余量高达48.36%,且燃烧残余物表面致密,显示出优异的耐火性能。

关 键 词:钢结构防火涂料  膨胀阻燃体系  埃洛石纳米管  协同效应  耐火性能  

Effect of Halloysite on the Fireproof Performance of Water-Based Ultrathin Intumescent Fireproof Coating for Steel Structures
Liu Fang,Sun Ling,Tang Wanxiong,Lan Fangwei,Jia Detain,Luo Yuanfang.Effect of Halloysite on the Fireproof Performance of Water-Based Ultrathin Intumescent Fireproof Coating for Steel Structures[J].Paint & Coatings Industry,2010,40(1).
Authors:Liu Fang  Sun Ling  Tang Wanxiong  Lan Fangwei  Jia Detain  Luo Yuanfang
Affiliation:1.College of Materials Science and Engineering;South China University of Technology;Guangzhou;Guangdong 510641;China;2.SunDa Chemical Technology Co.;Ltd;Zhongshan 528400;China
Abstract:The title water-based ultrathin intumescent fireproof coating for steel structures was prepared by using acrylic latex as binder,ammonium polyphosphate,melamine and pentaerythritol as main flame retardant,halloysite nanotube(HNTs) as flame retardant synergist.Its fireproof performance was investigated by simulated big panel combustion method and Cone Calorimeter.The surface morphology of char residues formed was characterized by SEM.The results showed that HNTs has greatly influence on fire-resisting perfor...
Keywords:fire-resistant coating for steel structures  intumescent flame retardant system  halloysite nanotube  synergistic effect  fire-resisting performance  
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