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Fabrication of magnetically recoverable Fe3O4/CdS/g-C3N4 photocatalysts for effective degradation of ciprofloxacin under visible light
Affiliation:1. School of Chemistry, Shoolini University, Solan, Himachal Pradesh 173229, India;2. College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen University, Shenzhen, 518055, PR China;3. College of Natural and Health Sciences, Zayed University, P.O. Box 144534, Abu Dhabi, United Arab Emirates;4. Department of Chemistry, College of Science, Building#5, King Saud University, Riyadh 11451, Saudi Arabia;1. Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P. O. Box. 87317-51167, Iran;2. Chemistry Department, College of Science, University of Raparin, Rania, Kurdistan Region, Iraq;3. Institute of Research and Development, Duy Tan University, Da Nang, 550000, Viet Nam;1. Department of Earth Resources Engineering, Faculty of Engineering, Kyushu University, 744 Motooka, Nishiku, Fukuoka 819-0395, Japan;2. Institute for Catalysis, Hokkaido University, Sapporo 001-0021, Japan;1. School of Chemistry, Shoolini University, Solan, Himachal Pradesh 173229, India;2. Department of Petroleum and Chemical Engineering, Faculty of Engineering, Sultan Qaboos University, Muscat, Oman;3. Department of Chemistry, College of Science, Building #5, King Saud University, Riyadh 11451, Saudi Arabia;4. College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen University, Shenzhen 518060, PR China
Abstract:Photocatalytic technology is an environmentally safe method of eliminating organic pollutants and antibiotics in wastewater. In this research, the performance of Fe3O4/CdS/g-C3N4 (FCN) photocatalyst for degradation of antibiotics was studied. The composite photocatalysts with different concentrations of g-C3N4 were prepared. FCN has better photocatalytic activity than degradation dyes in removal of antibiotics under visible light. This indicates that FCN could effectively hinder the recombination of carriers, and the addition of g-C3N4 increases the optical response range of CdS. At the same time, the introduction of Fe3O4 magnetic nanoparticles overcomes the problem of difficulty in recovery of the powder photocatalyst. The photocatalytic activity is not reduced to any significant after three cycles of use.
Keywords:Photocatalytic activity  Magnetic separation  Ciprofloxacin  Visible light
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