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Dealuminated Y Zeolite for Water-Driven Adsorption Heat Pumps: Hydrothermal Stability
Authors:Josef-Christian Buhl  Wolfgang Lutz  Thomas Herzog
Affiliation:1. Leibniz-Universität Hannover, Institut für Mineralogie, Callinstraße 3, 30167 Hannover, Germany;2. Brandenburgische Technische Universität Cottbus-Senftenberg, Volmerstraße 13, 12489 Berlin, Germany;3. Technische Hochschule Wildau, Hochschulring 1, 15745 Wildau, Germany
Abstract:Silica gel or zeolites AlPO-5 and SAPO-34 are recommended as adsorbents in water-driven heat pumps because of their selective water uptake. Secondary energy, like solar energy, can be used for regeneration of loaded adsorbers. In case of the availability of only low energy levels, the use of dealuminated Y zeolite (DAY) is the better choice because of the infinitely variation of its hydrophilic properties by tailoring of the framework Si/Al ratio. Actual data on the hydrothermal stability of DAY are lacking. Thus, we report on the long-term behavior of DAY zeolites with different Si/Al ratios.
Keywords:Adsorption  Dealumination  Heat pump  Hydrothermal stability  Zeolite Y
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