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煤与废塑料共热解特性研究进展
引用本文:张婷婷,白宗庆,侯冉冉,冯智皓,叶东鸿,郭振兴,孔令学,白进,李文.煤与废塑料共热解特性研究进展[J].化工进展,2021,40(5):2461-2470.
作者姓名:张婷婷  白宗庆  侯冉冉  冯智皓  叶东鸿  郭振兴  孔令学  白进  李文
作者单位:1.中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西 太原 030001;2.中国科学院大学,北京 100049
基金项目:国家自然科学基金(22078353);NSFC-新疆联合基金(U1703252);山西省重点研发计划(21903D421086)
摘    要:煤与塑料共热解既能回收废塑料中的碳氢资源,又可以实现废塑料的资源无害化处理,是一种很有前景的废塑料资源化回收利用方式。本文概述了煤与塑料共热解的热解特性及其产物性质,分析了煤与塑料共热解的机理及共热解过程中氯的迁移规律,简要介绍了煤和塑料的不同混合方式及其对共热解特性的影响。文中指出煤与塑料共热解具有明显的增油减水效应,在煤热解过程中添加一定量的废塑料不仅可以改善焦油品质,同时对热解半焦的结构和反应性也有一定的影响,因此煤-塑料共热解是一种绿色高效资源化的废塑料处理方式,对于废塑料循环利用、解决白色污染问题及提高煤炭利用率具有重要意义。

关 键 词:废塑料    共热解  碳氢资源  回收利用  
收稿时间:2020-06-28

Research progress on co-pyrolysis characteristics of coal and waste plastics
ZHANG Tingting,BAI Zongqing,HOU Ranran,FENG Zhihao,YE Donghong,GUO Zhenxing,KONG Lingxue,BAI Jin,LI Wen.Research progress on co-pyrolysis characteristics of coal and waste plastics[J].Chemical Industry and Engineering Progress,2021,40(5):2461-2470.
Authors:ZHANG Tingting  BAI Zongqing  HOU Ranran  FENG Zhihao  YE Donghong  GUO Zhenxing  KONG Lingxue  BAI Jin  LI Wen
Affiliation:1.State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China
2.University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:Co-pyrolysis of coal and plastics can recover the hydrocarbon resources in waste plastics and realize the harmless treatment of waste plastics, so it is a promising way to recycle waste plastics. In this paper, the pyrolysis characteristics and product properties during co-pyrolysis of coal and plastics were summarized, and the mechanism of co-pyrolysis and the transformation of chlorine during co-pyrolysis were analyzed. Furthermore, the different mixing modes of coal and plastics and their influence on co-pyrolysis characteristics were introduced. The co-pyrolysis of coal and plastics has obvious effect on increasing oil and reducing water. Adding a certain amount of waste plastics in the process of coal pyrolysis can improve the quality of tar, and impact the structure and reactivity of pyrolysis semicoke. Therefore, co-pyrolysis of coal and plastics is a green and efficient method to manage waste plastics, which is of great significance to recover waste plastics, solve white pollution problem and improve the utilization efficiency of coal.
Keywords:waste plastics  coal  co-pyrolysis  hydrocarbon resources  recovery  
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