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电位滴定法区分测定水中微量ClO2,Cl2,ClO2-及ClO3-的研究
引用本文:施来顺,胡德栋,谢永芳.电位滴定法区分测定水中微量ClO2,Cl2,ClO2-及ClO3-的研究[J].工业水处理,2003,23(4):57-60.
作者姓名:施来顺  胡德栋  谢永芳
作者单位:山东大学南校区化学与化工学院,山东,济南,250061
基金项目:山东省重点科技攻关项目(SD98-25)
摘    要:利用自动电位滴定仪分别测定了NaClO2固体质量浓度为20mg/L,10mg/L,5mg/L,2.5mg/L,,1mg/L和NaClO23(与盐酸反应)质量浓度为20mg/L,10mg/L,5mg/L,2.5mg/L,,1mg/L的水样,分别求出其回收率及检出限。试验表明电位滴定法能在5mg/L以上质量尝试快速准确的区分测定ClO2,Cl2,ClO2^-和ClO3^-。

关 键 词:电位滴定法  二氧化氯  质量浓度  饮用水  水质监测
文章编号:1005-829X(2003)04-0057-04
修稿时间:2002年8月28日

Researches on the determination of chlorine dioxide, chlorine, chlorite and chlorate in water by potentiometric titriation method
Shi Laishun,Hu Dedong,Xie Yongfang.Researches on the determination of chlorine dioxide, chlorine, chlorite and chlorate in water by potentiometric titriation method[J].Industrial Water Treatment,2003,23(4):57-60.
Authors:Shi Laishun  Hu Dedong  Xie Yongfang
Abstract:The solid sodium chlorite contents of 20,10,5,2.5 ,1 mg/L and the sodium chlorate (reacted with hydrochloric acid) contents of 20,10,5,2.5,1 mg/L in water samples are determined respectively by autopotentiometric titrator. The recovery rates and detection limits are figured out, respectively. All these show that the potentiometric titrimetry can determine chlorine dioxide, chlorine, chlorite and chlorate at more than 5 mg/L in water quickly and accurately.
Keywords:potentiometric titrimetry  chlorine dioxide  concentration
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