| 聚乙二醇/聚(β-羟基丁酸酯)两嵌段共聚物的合成及表征 |
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| 引用本文： | 许峰,冷兵,马健岩,王利凤,曾宇平.聚乙二醇/聚(β-羟基丁酸酯)两嵌段共聚物的合成及表征[J].应用化工,2009,28(1). |
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| 作者姓名： | 许峰 冷兵 马健岩 王利凤 曾宇平 |
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| 作者单位： | 沈阳建筑大学,材料科学与工程学院,辽宁,沈阳,110168 |
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| 摘 要： | 为改进聚(β-羟基丁酸酯)(PHB)的结晶性和亲水性,通过聚乙二醇单甲醚(MPEG)的端酰氯基团和聚(β-羟基丁酸酯)的端羟基基团的官能团反应,制备了聚乙二醇/聚(β-羟基丁酸酯)两嵌段共聚物。通过红外光谱、核磁、X射线衍射、差热分析和凝胶渗透色谱等手段,证明制备了嵌段共聚物。吸水实验表明,材料的亲水性得到了明显的改善。
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| 关 键 词： | 聚乙二醇 聚(β-羟基丁酸酯) 共聚物 |
Synthesis and characterization of poly (ethylene glycol)/poly (β-hydroxybutyrate) diblock copolymer |
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| XU Feng,LENG Bing,MA Jian-yan,WANG Li-feng,ZENG Yu-ping.Synthesis and characterization of poly (ethylene glycol)/poly (β-hydroxybutyrate) diblock copolymer[J].Applied chemical industry,2009,28(1). |
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| Authors: | XU Feng LENG Bing MA Jian-yan WANG Li-feng ZENG Yu-ping |
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| Abstract: | For improving the crystalline properties and hydrophilicity of the poly(β-hydroxybutyrate),poly(ethylene glycol) /poly(β-hydroxybutyrate) diblock copolymer was synthesized by the coupling reaction between hydroxyl-terminated poly(β-hydroxybutyrate) and acylate-terminated poly(ethylene glycol) monomethyl ether.The diblock copolymer was characterized by IR,1H NMR,X-ray analysis,DSC,and GPC.The result of water uptake suggested that the hydrophilicity of PHB was improved by the introduction of the MPEG segment. |
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| Keywords: | poly(ethylene glycol) poly(β-hydroxybutyrate) copolymer |
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