| 碳酸甲苯酯的合成及光谱研究 |
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| 引用本文： | 谢育红,朱大建,梅付名,王庶,李光兴.碳酸甲苯酯的合成及光谱研究[J].化学试剂,2006,28(12):705-707. |
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| 作者姓名： | 谢育红 朱大建 梅付名 王庶 李光兴 |
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| 作者单位： | 华中科技大学,化学系,湖北,武汉,430074 |
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| 基金项目： | 国家“863”计划资助项目(2004AA32G020) |
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| 摘 要： | 通过苯酚和碳酸二甲酯的酯交换反应合成了碳酸甲苯酯,采用减压精馏对其进行了分离提纯,得到纯度>99.5%的碳酸甲苯酯;运用红外光谱、紫外光谱、核磁共振氢谱以及质谱对其结构进行了表征,并对其光谱数据进行了解析。
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| 关 键 词： | 碳酸甲苯酯 酯交换 红外光谱 紫外光谱 核磁共振氢谱 质谱 |
| 文章编号： | 0258-3283（2006）12-0705-03 |
| 收稿时间： | 2006-05-17 |
| 修稿时间： | 2006-05-17 |
Study on synthesis of methyl phenyl carbonate and its spectral properties |
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| XIE Yu-hong,ZHU Da-jian,MEI Fu-ming,WANG Shu,LI Guang-xing.Study on synthesis of methyl phenyl carbonate and its spectral properties[J].Chemical Reagents,2006,28(12):705-707. |
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| Authors: | XIE Yu-hong ZHU Da-jian MEI Fu-ming WANG Shu LI Guang-xing |
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| Affiliation: | Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074,China |
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| Abstract: | Methyl phenyl carbonate(MPC) was prepared by transesterification of dimethyl carbonate(DMC) with phenol and the product with a purity exceeding 99.5% was obtained by vacuum distillation.The structure of the product was identified to be MPC by IR,UV,(()~1HNMR),MS spectrometry,and the spectral data were interpreted. |
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| Keywords: | methyl phenyl carbonate transesterification IR UV (()~1HNMR) MS |
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