| 天然手性环状萜烯化合物松脂高沸点组分反应分离的研究 |
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| 引用本文： | 刘红军,周永红,郭晓昕,冯国东.天然手性环状萜烯化合物松脂高沸点组分反应分离的研究[J].化学试剂,2010,32(4). |
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| 作者姓名： | 刘红军 周永红 郭晓昕 冯国东 |
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| 作者单位： | 1. 中国林业科学研究院,林产化学工业研究所,江苏,南京,210042
2. 国家林业局,林产化学工程重点开放性实验室,江苏,南京,210042 |
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| 摘 要： | 利用天然手性环状萜烯化合物资源中松脂的高沸点组分,通过反应分离方法,得到高纯度的长叶烯、异长叶烯、β-石竹烯醇和枞酸,其样品纯度使用GC、HPLC测定分别是95.12%、98.37%、99.75%、99.15%,分离得率基本达到80%以上.分离产物通过~1HNMR、MS、IR测定分析进行了表征.
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| 关 键 词： | 松脂 反应分离 长叶烯 异长叶烯 β-石竹烯醇 枞酸 β-caryphyllenol |
Separation of natural chiral cyclic terpenoid compounds from high-boiling components of rosin |
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| LIU Hong-jun,ZHOU Yong-hong,GUO Xiao-xin,FENG Guo-dong.Separation of natural chiral cyclic terpenoid compounds from high-boiling components of rosin[J].Chemical Reagents,2010,32(4). |
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| Authors: | LIU Hong-jun ZHOU Yong-hong GUO Xiao-xin FENG Guo-dong |
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| Abstract: | The natural chiral cyclic terpenoid compounds,such as longifolene,isolongifolene,β-caryphyllenol,and abietic acid,were obtained from high boiling components of rosin via reaction and separation processes.The purity of longifolene,isolongifolene,β-caryphyllenol,and abietic acid was 95.12%,98.37%,99.75%,and 99.15%,respectively,as determined by GC and HPLC.The product yield after separation was over 80%.The products were characterized by ~1HNMR,MS,and IR spectroscopies. |
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| Keywords: | rosin reaction and separation longifolene isolongifolene abietic acid |
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