| 微量活性引发剂促进惰性引发剂引发环氧乙烷的开环聚合速率研究 |
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| 引用本文： | 翟慕衡,陆晓晶,张莉,杜宝辉,沈良骏.微量活性引发剂促进惰性引发剂引发环氧乙烷的开环聚合速率研究[J].化学世界,2005,46(4):195-198,237. |
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| 作者姓名： | 翟慕衡 陆晓晶 张莉 杜宝辉 沈良骏 |
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| 作者单位： | 安徽师范大学化学与材料科学学院,安徽,芜湖,241000 |
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| 基金项目： | 安徽省教委自然科学基金资助项目(2001kj094) |
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| 摘 要： | 研究了利用微量更活泼的阴离子引发剂促进具引发惰性的磺胺嘧啶钠引发环氧乙烷开环聚合的反应速度，作了系列比较，并讨论了其影响速率的机制。
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| 关 键 词： | 开环聚合 阴离子引发剂 环氧乙烷 速率 |
| 文章编号： | 0367-6358(2005)04-195-04 |
Study on the Promoting Effect of Trace Amount of Active Initiator on the Rate of Ring-opening Polymerization of Ethylene Oxide with an Inert Initiator |
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| ZHONG Mu-heng,LU Xiao-jing,ZHANG Li,DU Bao-hui,SHEN Liang-jun.Study on the Promoting Effect of Trace Amount of Active Initiator on the Rate of Ring-opening Polymerization of Ethylene Oxide with an Inert Initiator[J].Chemical World,2005,46(4):195-198,237. |
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| Authors: | ZHONG Mu-heng LU Xiao-jing ZHANG Li DU Bao-hui SHEN Liang-jun |
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| Abstract: | Adding a trace amount of active initiator into the inert initiator SF-Na, the rate of ring-opening polymerization of ethylene oxide was promoted. The promoting mechanism was discussed. |
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| Keywords: | ring-opening polymerization anionic initiator ethylene oxide reaction rate |
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