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制备条件对新颖负载型TiO_2光催化剂活性的影响
引用本文:戴智铭,陈爱平,陶咏,古宏晨,顾明元.制备条件对新颖负载型TiO_2光催化剂活性的影响[J].化学世界,2002,43(3):115-119.
作者姓名:戴智铭  陈爱平  陶咏  古宏晨  顾明元
作者单位:1. 华东理工大学教育部超细材料制备与应用国家重点实验室,上海,200237上海交通大学金属基复合材料国家重点实验室,上海,200030
2. 华东理工大学教育部超细材料制备与应用国家重点实验室,上海,200237
3. 上海交通大学金属基复合材料国家重点实验室,上海,200030
基金项目:国家自然科学基金资助项目(29636010);上海市重大创新项目(995211001).
摘    要:开发新颖玻璃弹簧填料型载体 ,采用浸渍 -烧结法制备纳米 Ti O2 负载型光催化剂 ,研究不同制备条件对其催化活性的影响。结果表明 ,该负载型催化剂较佳制备条件为 :P2 5 Ti O2 浸渍浆料浓度为 0 .5 % ,浸渍次数为 5次 ,焙烧温度为 40 0°C、时间为 3 h。该负载型光催化剂具有高的光照射表面积 /体积比、空隙率很大、床层压降低 ,以及在催化剂填充空间光辐射分布较均匀 ,导致有效的光催化反应体积成倍增加的优点。

关 键 词:半导体  光催化  二氧化钛  光催化活性
文章编号:0367-6358(2002)03-0115-05

Effect of Preparation Conditions on the Catalytic Activity of Novel Immobilized Photocatalyst
DAI Zhi ming ,CHEN Ai ping ,TAO Yong ,GU Hong chen ,GU Ming yuan.Effect of Preparation Conditions on the Catalytic Activity of Novel Immobilized Photocatalyst[J].Chemical World,2002,43(3):115-119.
Authors:DAI Zhi ming    CHEN Ai ping  TAO Yong  GU Hong chen  GU Ming yuan
Affiliation:DAI Zhi ming 1,2,CHEN Ai ping 1,TAO Yong 1,GU Hong chen 1,GU Ming yuan 2
Abstract:A novel support of glass spring was developed, and the TiO 2 immobilized photocatalyst was prepared by using dipcoating method. The effect of different preparation conditions on the photocatalytic activity of TiO 2/glass spring catalyst was studied. The results showed that the photocatalytic activity of TiO 2/glass spring was the highest when the slurry concentration of P25 TiO 2 was 0.5%, the times of dip coating was five, and the heat treatment was earried out at 400°C for three hours. The TiO 2/glass spring has the advantage of high illuminated surface area, good mass transfer, low pressure drop, uniform light distribution, minimal transport resistance, and high depth of penetration of UV light.
Keywords:semiconductor  photocatalysis  titanium dioxide  photocatalytic activity  
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