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钛酸钾晶须的表面改性及其在隔热卷材涂料中的应用
引用本文:王鹏,程江,文秀芳,皮丕辉,蔡智奇,杨卓如.钛酸钾晶须的表面改性及其在隔热卷材涂料中的应用[J].电镀与涂饰,2010,29(10):51-55.
作者姓名:王鹏  程江  文秀芳  皮丕辉  蔡智奇  杨卓如
作者单位:华南理工大学化学与化工学院,广东广州,510640;华南理工大学化学与化工学院,广东广州,510640;华南理工大学化学与化工学院,广东广州,510640;华南理工大学化学与化工学院,广东广州,510640;华南理工大学化学与化工学院,广东广州,510640;华南理工大学化学与化工学院,广东广州,510640
摘    要:利用硅烷偶联剂KH-570对表面无机包覆SiO2前、后的六钛酸钾晶须(PTW)进行有机表面改性,比较了硅烷偶联剂改性无机包覆SiO2处理前、后的PTW对卷材涂料隔热性能的影响.采用红外光谱(IR)、热重分析(TG)方法对改性前后的PTW进行了表征.结果表明,SiO2以化学键键合在PTW表面,KH-570在PTW表面形成了有机包覆层.涂膜隔热性能测试结果表明,以9%SiO2包覆处理后再用偶联剂KH-570改性的PTW能明显改善隔热卷材涂料的隔热性能,其热反射率达到75.4%,比不含PTW的漆膜提高了34.4个百分点,比含直接用偶联剂KH-570改性的PTW的漆膜提高了12.8个百分点.

关 键 词:隔热涂料  六钛酸钾晶须  硅烷偶联剂  改性  热反射率

Surface modification of potassium titanate whisker and its application to thermal insulation coil coatings
WANG Peng,CHENG Jiang,WEN Xiu-fang,PI Pi-hui,CAI Zhi-qi,YANG Zhuo-ru.Surface modification of potassium titanate whisker and its application to thermal insulation coil coatings[J].Electroplating & Finishing,2010,29(10):51-55.
Authors:WANG Peng  CHENG Jiang  WEN Xiu-fang  PI Pi-hui  CAI Zhi-qi  YANG Zhuo-ru
Affiliation:WANG Peng,CHENG Jiang,WEN Xiu-fang,PI Pi-hui,CAI Zhi-qi,YANG Zhuo-ru School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,China
Abstract:Potassium titanate whiskers(PTW) were modified by silane coupling agent KH-570 before and after coating with inorganic SiO2.The influence of the PTWs modified by silane coupling agent before and after coating with SiO2 on thermal insulation performance of coil coating were compared.PTWs before and after modification were characterized by infrared(IR) spectroscopy and thermo-gravimetry(TG).The results indicated that SiO2 is bound on the surface of PTW with chemical bond and an organic coating layer of KH-570...
Keywords:heat insulation coating  potassium titanate whisker  silane coupling agent  modification  heat reflectivity  
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