RFL coated aramid short fiber reinforced thermoplastic elastomer: Mechanical, rheological and morphological characteristics |
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Authors: | G S Shibulal Kinsuk Naskar |
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Affiliation: | (1) Rubber Technology Centre, Indian Institute of Technology, Kharagpur, 721302, West Bengal, India; |
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Abstract: | Composite based on a new generation metallocene catalyzed thermoplastic elastomer ethylene-octene copolymer (EOC) and resorcinol
formaldehyde latex (RFL) coated aramid short fiber was prepared by varying the short fiber loading from 1 to 10 phr. The mechanical,
morphological and rheological characterizations were carried out. The impact of a low molecular weight maleic anhydride grafted
1, 2 polybutadiene (MA-g-PB) on various properties was also investigated. It has been observed that with increasing the short
fiber content both the low strain modulus and modulus at 100% increase but the tensile strength and elongation at break decrease.
The improvements in tensile strength coupled with elongation at break and good fiber dispersion particularly at high fiber
loaded composite were achieved with the incorporation of MA-g-PB, which indicates that it acts as an interface modifier through
compatibilization between the fiber and the EOC matrix as well as a good dispersing agent. The understanding of adhesion between
the fiber and the polymer and the sticking of polymer traces on the tensile fractured fiber surface of the composite by scanning
electron microscopic analyses further support the compatibilizing action of MA-g-PB. The melt rheological behavior such as
storage modulus, loss modulus, complex viscosity and storage viscosity of the composites were investigated using a Rubber
Process Analyser (RPA) under strain and frequency sweep mode. |
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