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陶瓷膜的三步法清洗及效果分析
引用本文:黄有泉,武云龙,付馨,王磊,赵晓非.陶瓷膜的三步法清洗及效果分析[J].工业用水与废水,2011,42(6):43-47,62.
作者姓名:黄有泉  武云龙  付馨  王磊  赵晓非
作者单位:1. 大庆油田有限责任公司第五采油厂,黑龙江大庆,163513
2. 东北石油大学化学化工学院石油与天然气化工省重点实验室,黑龙江大庆,163318
摘    要:采用超滤膜处理油田采出污水,通过陶瓷膜和篮式过滤器上无机垢的组成及陶瓷膜SEM形貌分析,研究了陶瓷膜清洗过程中药剂及离子浓度的变化、跨膜压差的变化等参数,考察了膜运行过程中的跨膜压差和产水量的变化情况.确定了具有针对性的碱洗-络合剂洗-氧化剂洗三步法清洗对污染的ZrO2陶瓷膜进行40℃低温清洗.中试试验结果表明清洗后,...

关 键 词:陶瓷膜  油田采出污水  膜污染  无机垢  膜清洗

Study on three-step cleaning of ceramic membrane and analysis of its effects
HUANG You-quan,WU Yun-long,FU Xin,WANG Lei,ZHAO Xiao-fei.Study on three-step cleaning of ceramic membrane and analysis of its effects[J].Industrial Water & Wastewater,2011,42(6):43-47,62.
Authors:HUANG You-quan  WU Yun-long  FU Xin  WANG Lei  ZHAO Xiao-fei
Affiliation:1.No.5 Oil Production Plant,Daqing Oilfield Company Ltd.,Petrochina,Daqing 163513,China;2.Provincial Key Laboratory of Oil and Gas Chemical Technology,Collegte of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,China)
Abstract:Ultrafiltration membrane was used to treat oilfield produced water.According to the analysis of the composition of inorganic scales on ceramic membrane and basket strainer and the SEM photos of the ceramic membrane′s cross section,the variation of parameters such as: reagent and ion concentration,transmembrane pressure and so on during the course of cermic membrane cleaning were studied;meanwhile,the variation of transmembrane pressure and water production during the membrane operation were also investigated.The alkali-complexing agent-oxidizer three-step washing was finally determined to be the proper process for fouled ZrO2 ceramic membrane cleaning at a temperature of 40 ℃.The results of the pilot scale test showed that,after the cleaning,the recovery rates of membrane flux at high and low pressure terminals were 97.1% and 116.8% respectively,the maximum operation time reached 68 h.The said process had a good repeatability,moreover,the advantages of it on aspects of cost control,operating condition,cleaning effect and so on were also obvious.
Keywords:ceramic membrane  oilfield produced water  membrane fouling  inorganic scale  membrane washing
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